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🧪 Chemistry  ·  Coordination Compounds  ·  NEET & JEE

The formula for potassium hexacyanoferrate(III) is:

Answer: K3[Fe(CN) 6 ].

  • A K3[Fe(CN)<sub>6</sub>]
  • B K<sub>4</sub>[Fe(CN)<sub>6</sub>]
  • C K[Fe(CN)<sub>6</sub>]
  • D K2[Fe(CN)<sub>6</sub>]

Correct answer: A. K3[Fe(CN)<sub>6</sub>]

Explanation: Fe is +3, each CN- is -1, so 6 CN- = -6; total complex charge = +3 - 6 = -3; 3 K+ needed to balance.

Octahedralcoordination no. 6e.g. [Co(NH3)6]3+Tetrahedralcoordination no. 4e.g. [Ni(CO)4]Square Planarcoordination no. 4e.g. [Pt(NH3)2Cl2]

The three common coordination geometries: octahedral (6 ligands), tetrahedral (4 ligands), and square planar (4 ligands in one plane).

Concept context

Study of compounds where a central metal atom is bonded to surrounding ligands. Covers nomenclature, types of isomerism, bonding theories (VBT, CFT), and applications in medicine, photography, and industry.

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