Zaymiey

🧪 Chemistry  ·  Haloalkanes & Haloarenes  ·  NEET & JEE

Which of the following pairs of compounds are enantiomers?

Answer: (R)-2-chlorobutane and (S)-2-chlorobutane.

  • A (R)-2-chlorobutane and (S)-2-chlorobutane
  • B (R)-2-chlorobutane and (R)-2-chlorobutane
  • C Meso-2,3-dichlorobutane and (R,R)-2,3-dichlorobutane
  • D 1-chlorobutane and 2-chlorobutane

Correct answer: A. (R)-2-chlorobutane and (S)-2-chlorobutane

Explanation: Enantiomers are non-superimposable mirror images with opposite configurations at all chiral centres. (R)- and (S)-2-chlorobutane are mirror images with opposite configurations at C-2.

SN2: one stepNu-CX-backside attackNuC+ X-Inversion of configuration(Walden inversion)SN1: two stepsCX-slow: leaving group exits+CcarbocationNu-Planar intermediate givesracemisation (both faces attacked)

SN2 proceeds in a single step with backside attack and inversion of configuration, while SN1 forms a planar carbocation intermediate first, leading to racemisation.

Concept context

Study carbon-halogen compounds: how they are made, how they react via SN1/SN2 and elimination, their stereochemistry, and their environmental impact.

Read the full Haloalkanes & Haloarenes notes →