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🧪 Chemistry  ·  Haloalkanes & Haloarenes  ·  NEET & JEE

Which of the following haloalkanes is most reactive toward the SN2 mechanism?

Answer: CH 3 Br.

  • A (CH<sub>3</sub>)3CBr
  • B (CH<sub>3</sub>)2CHBr
  • C CH<sub>3</sub>CH<sub>2</sub>Br
  • D CH<sub>3</sub>Br

Correct answer: D. CH<sub>3</sub>Br

Explanation: SN2 rate: methyl > primary > secondary > tertiary. CH₃Br has essentially no steric hindrance at the reaction centre; it reacts fastest in SN2.

SN2: one stepNu-CX-backside attackNuC+ X-Inversion of configuration(Walden inversion)SN1: two stepsCX-slow: leaving group exits+CcarbocationNu-Planar intermediate givesracemisation (both faces attacked)

SN2 proceeds in a single step with backside attack and inversion of configuration, while SN1 forms a planar carbocation intermediate first, leading to racemisation.

Concept context

Study carbon-halogen compounds: how they are made, how they react via SN1/SN2 and elimination, their stereochemistry, and their environmental impact.

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