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🧪 Chemistry  ·  Haloalkanes & Haloarenes  ·  NEET & JEE

What type of bond does a Grignard reagent (RMgX) contain?

Answer: Polar covalent C-Mg bond with C acting as nucleophile.

  • A Polar covalent C-Mg bond with C acting as nucleophile
  • B A largely ionic bond between a carbanion and the magnesium cation
  • C A non-polar covalent bond identical to a C-C bond in alkanes
  • D A mainly dative bond donated from magnesium toward the carbon atom

Correct answer: A. Polar covalent C-Mg bond with C acting as nucleophile

Explanation: The C-Mg bond in a Grignard reagent is strongly polarised (Mg is more electropositive), making the carbon nucleophilic (carbanion character).

SN2: one stepNu-CX-backside attackNuC+ X-Inversion of configuration(Walden inversion)SN1: two stepsCX-slow: leaving group exits+CcarbocationNu-Planar intermediate givesracemisation (both faces attacked)

SN2 proceeds in a single step with backside attack and inversion of configuration, while SN1 forms a planar carbocation intermediate first, leading to racemisation.

Concept context

Study carbon-halogen compounds: how they are made, how they react via SN1/SN2 and elimination, their stereochemistry, and their environmental impact.

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