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🧪 Chemistry  ·  Haloalkanes & Haloarenes  ·  NEET & JEE

Which chloromethane, once marketed as pyrene, was formerly used as a fire extinguisher?

Answer: CCl 4.

  • A CCl<sub>4</sub>
  • B CH<sub>2</sub>Cl<sub>2</sub>
  • C CHI<sub>3</sub>
  • D CHCl<sub>3</sub>

Correct answer: A. CCl<sub>4</sub>

Explanation: Carbon tetrachloride (CCl<sub>4</sub>), sold as pyrene, was used to smother fires as its dense vapour cuts off oxygen.

SN2: one stepNu-CX-backside attackNuC+ X-Inversion of configuration(Walden inversion)SN1: two stepsCX-slow: leaving group exits+CcarbocationNu-Planar intermediate givesracemisation (both faces attacked)

SN2 proceeds in a single step with backside attack and inversion of configuration, while SN1 forms a planar carbocation intermediate first, leading to racemisation.

Concept context

Study carbon-halogen compounds: how they are made, how they react via SN1/SN2 and elimination, their stereochemistry, and their environmental impact.

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