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🧪 Chemistry  ·  Haloalkanes & Haloarenes  ·  NEET & JEE

The Wurtz-Fittig reaction of an aryl halide with an alkyl halide and sodium in dry ether gives:

Answer: an alkylarene.

  • A a biaryl
  • B an alkylarene
  • C a symmetrical ether
  • D an alkane

Correct answer: B. an alkylarene

Explanation: Wurtz-Fittig couples an aryl halide with an alkyl halide to give an alkyl-substituted arene; coupling of two aryl halides (Fittig) gives a biaryl.

SN2: one stepNu-CX-backside attackNuC+ X-Inversion of configuration(Walden inversion)SN1: two stepsCX-slow: leaving group exits+CcarbocationNu-Planar intermediate givesracemisation (both faces attacked)

SN2 proceeds in a single step with backside attack and inversion of configuration, while SN1 forms a planar carbocation intermediate first, leading to racemisation.

Concept context

Study carbon-halogen compounds: how they are made, how they react via SN1/SN2 and elimination, their stereochemistry, and their environmental impact.

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