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🧪 Chemistry  ·  Haloalkanes & Haloarenes  ·  NEET & JEE

The reactivity of haloalkanes toward SN2 reaction follows the order:

Answer: 1° > 2° > 3°.

  • A 3° > 2° > 1°
  • B 1° > 2° > 3°
  • C 2° > 1° > 3°
  • D All are equal

Correct answer: B. 1° > 2° > 3°

Explanation: SN2 is hindered by steric bulk; primary haloalkanes have the least steric hindrance so they react fastest in SN2.

SN2: one stepNu-CX-backside attackNuC+ X-Inversion of configuration(Walden inversion)SN1: two stepsCX-slow: leaving group exits+CcarbocationNu-Planar intermediate givesracemisation (both faces attacked)

SN2 proceeds in a single step with backside attack and inversion of configuration, while SN1 forms a planar carbocation intermediate first, leading to racemisation.

Concept context

Study carbon-halogen compounds: how they are made, how they react via SN1/SN2 and elimination, their stereochemistry, and their environmental impact.

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