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🧪 Chemistry  ·  Haloalkanes & Haloarenes  ·  NEET & JEE

The reaction of an alkyl halide RX with Mg in dry ether gives a Grignard reagent. This reaction fails if:

Answer: Moisture or oxygen is present.

  • A The solvent is dry ether
  • B Excess Mg is used
  • C Moisture or oxygen is present
  • D The alkyl halide is primary

Correct answer: C. Moisture or oxygen is present

Explanation: Water destroys the Grignard reagent: RMgX + H₂O → RH + Mg(OH)X. Oxygen can also oxidise it. Strictly anhydrous, inert conditions are essential.

SN2: one stepNu-CX-backside attackNuC+ X-Inversion of configuration(Walden inversion)SN1: two stepsCX-slow: leaving group exits+CcarbocationNu-Planar intermediate givesracemisation (both faces attacked)

SN2 proceeds in a single step with backside attack and inversion of configuration, while SN1 forms a planar carbocation intermediate first, leading to racemisation.

Concept context

Study carbon-halogen compounds: how they are made, how they react via SN1/SN2 and elimination, their stereochemistry, and their environmental impact.

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