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🧪 Chemistry  ·  Haloalkanes & Haloarenes  ·  NEET & JEE

The reaction of a Grignard reagent (RMgBr) with CO<sub>2</sub> followed by hydrolysis gives:

Answer: A carboxylic acid.

  • A An alcohol
  • B A ketone
  • C An ester
  • D A carboxylic acid

Correct answer: D. A carboxylic acid

Explanation: RMgBr + CO₂ → RCO₂MgBr; hydrolysis (H₃O⁺) gives RCOOH, a carboxylic acid. This is a useful chain-extension reaction.

SN2: one stepNu-CX-backside attackNuC+ X-Inversion of configuration(Walden inversion)SN1: two stepsCX-slow: leaving group exits+CcarbocationNu-Planar intermediate givesracemisation (both faces attacked)

SN2 proceeds in a single step with backside attack and inversion of configuration, while SN1 forms a planar carbocation intermediate first, leading to racemisation.

Concept context

Study carbon-halogen compounds: how they are made, how they react via SN1/SN2 and elimination, their stereochemistry, and their environmental impact.

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