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🧪 Chemistry  ·  Haloalkanes & Haloarenes  ·  NEET & JEE

The boiling point of haloalkanes compared to the parent alkane of similar molar mass is:

Answer: Higher.

  • A Much lower
  • B Similar
  • C The same
  • D Higher

Correct answer: D. Higher

Explanation: Haloalkanes have higher boiling points than comparable alkanes because C-X dipoles contribute stronger intermolecular attractions.

SN2: one stepNu-CX-backside attackNuC+ X-Inversion of configuration(Walden inversion)SN1: two stepsCX-slow: leaving group exits+CcarbocationNu-Planar intermediate givesracemisation (both faces attacked)

SN2 proceeds in a single step with backside attack and inversion of configuration, while SN1 forms a planar carbocation intermediate first, leading to racemisation.

Concept context

Study carbon-halogen compounds: how they are made, how they react via SN1/SN2 and elimination, their stereochemistry, and their environmental impact.

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