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🧪 Chemistry  ·  Haloalkanes & Haloarenes  ·  NEET & JEE

Freons are used as refrigerants but are harmful because they:

Answer: Release chlorine radicals that catalytically destroy the ozone layer.

  • A React with atmospheric water vapour to generate hydrochloric acid directly
  • B Release chlorine radicals that catalytically destroy the ozone layer
  • C Are acutely toxic to humans even at very low inhaled concentrations
  • D Dissolve readily in rainwater, directly causing acid rain over cities

Correct answer: B. Release chlorine radicals that catalytically destroy the ozone layer

Explanation: Freons (CFCs) are photolytically cleaved in the stratosphere, releasing Cl• radicals. Each Cl• can destroy thousands of O₃ molecules catalytically.

SN2: one stepNu-CX-backside attackNuC+ X-Inversion of configuration(Walden inversion)SN1: two stepsCX-slow: leaving group exits+CcarbocationNu-Planar intermediate givesracemisation (both faces attacked)

SN2 proceeds in a single step with backside attack and inversion of configuration, while SN1 forms a planar carbocation intermediate first, leading to racemisation.

Concept context

Study carbon-halogen compounds: how they are made, how they react via SN1/SN2 and elimination, their stereochemistry, and their environmental impact.

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