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🧪 Chemistry  ·  Coordination Compounds  ·  NEET & JEE

Which of the following statements about EDTA (ethylenediaminetetraacetate) is correct?

Answer: It is hexadentate (2 N + 4 O donor atoms) and forms thermodynamically very stable 1:1 chelates with most metal ions.

  • A It is hexadentate (2 N + 4 O donor atoms) and forms thermodynamically very stable 1:1 chelates with most metal ions
  • B It is generally bidentate, donating through mainly two of its six potential donor atoms according to conventional understanding
  • C It is said to bind mainly to transition metal ions and not to any s-block cations in routine practice overall
  • D It is said to become notably unstable once the surrounding solution pH rises above 7 in most cases under typical conditions

Correct answer: A. It is hexadentate (2 N + 4 O donor atoms) and forms thermodynamically very stable 1:1 chelates with most metal ions

Explanation: EDTA<sup>4-</sup> is hexadentate with 6 donor atoms; it forms kinetically stable, soluble chelate complexes (log Kf for Ca<sup>2+</sup>: 10.7; Fe<sup>3+</sup>: 25.1) over a wide pH range.

Octahedralcoordination no. 6e.g. [Co(NH3)6]3+Tetrahedralcoordination no. 4e.g. [Ni(CO)4]Square Planarcoordination no. 4e.g. [Pt(NH3)2Cl2]

The three common coordination geometries: octahedral (6 ligands), tetrahedral (4 ligands), and square planar (4 ligands in one plane).

Concept context

Study of compounds where a central metal atom is bonded to surrounding ligands. Covers nomenclature, types of isomerism, bonding theories (VBT, CFT), and applications in medicine, photography, and industry.

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