Zaymiey

🧪 Chemistry  ·  Coordination Compounds  ·  NEET & JEE

Which complex shows the trans effect most prominently?

Answer: Square planar Pt(II) complexes.

  • A Square planar Pt(II) complexes
  • B Octahedral Co(III) as widely reported
  • C Tetrahedral Ni(II) in standard practice
  • D Linear Au(I) under most conditions encountered

Correct answer: A. Square planar Pt(II) complexes

Explanation: The trans effect (kinetic lability of a ligand trans to another) is most pronounced and best studied in square planar Pt(II) complexes.

Octahedralcoordination no. 6e.g. [Co(NH3)6]3+Tetrahedralcoordination no. 4e.g. [Ni(CO)4]Square Planarcoordination no. 4e.g. [Pt(NH3)2Cl2]

The three common coordination geometries: octahedral (6 ligands), tetrahedral (4 ligands), and square planar (4 ligands in one plane).

Concept context

Study of compounds where a central metal atom is bonded to surrounding ligands. Covers nomenclature, types of isomerism, bonding theories (VBT, CFT), and applications in medicine, photography, and industry.

Read the full Coordination Compounds notes →