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🧪 Chemistry  ·  Coordination Compounds  ·  NEET & JEE

What is the IUPAC name for [Fe(CN)<sub>6</sub>]4-?

Answer: Hexacyanoferrate(II) ion.

  • A Hexacyanoferrate(II) ion
  • B Hexacyanoferrate(III) ion
  • C Iron hexacyanide
  • D Ferrocyanide

Correct answer: A. Hexacyanoferrate(II) ion

Explanation: Fe is in +2 oxidation state (hexacyanoferrate(II)): 6 CN- = -6; charge = -4; x - 6 = -4, x = +2.

Octahedralcoordination no. 6e.g. [Co(NH3)6]3+Tetrahedralcoordination no. 4e.g. [Ni(CO)4]Square Planarcoordination no. 4e.g. [Pt(NH3)2Cl2]

The three common coordination geometries: octahedral (6 ligands), tetrahedral (4 ligands), and square planar (4 ligands in one plane).

Concept context

Study of compounds where a central metal atom is bonded to surrounding ligands. Covers nomenclature, types of isomerism, bonding theories (VBT, CFT), and applications in medicine, photography, and industry.

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