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🧪 Chemistry  ·  Coordination Compounds  ·  NEET & JEE

What does VBT (Valence Bond Theory) explain about coordination compounds?

Answer: Hybridisation of metal orbitals and geometry; doesn't explain colour or magnetism well.

  • A Hybridisation of metal orbitals and geometry; doesn't explain colour or magnetism well
  • B Every property of the complex, including its colour and magnetism in full detail
  • C Mainly the magnetic behaviour of the complex and nothing else as frequently observed in practice
  • D Mainly the kinetics and reaction rates of the complex's ligand exchange in many documented cases

Correct answer: A. Hybridisation of metal orbitals and geometry; doesn't explain colour or magnetism well

Explanation: VBT explains shape and hybridisation of complexes but fails to satisfactorily explain colour (d-d transitions) and paramagnetism in a quantitative way.

Octahedralcoordination no. 6e.g. [Co(NH3)6]3+Tetrahedralcoordination no. 4e.g. [Ni(CO)4]Square Planarcoordination no. 4e.g. [Pt(NH3)2Cl2]

The three common coordination geometries: octahedral (6 ligands), tetrahedral (4 ligands), and square planar (4 ligands in one plane).

Concept context

Study of compounds where a central metal atom is bonded to surrounding ligands. Covers nomenclature, types of isomerism, bonding theories (VBT, CFT), and applications in medicine, photography, and industry.

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