Zaymiey

🧪 Chemistry  ·  Coordination Compounds  ·  NEET & JEE

The spin-only magnetic moment of [Fe(CN)<sub>6</sub>]<sup>3-</sup> is approximately:

Answer: 1.73 BM.

  • A 3.87 BM
  • B 1.73 BM
  • C 4.90 BM
  • D 5.92 BM

Correct answer: B. 1.73 BM

Explanation: Fe<sup>3+</sup> is d<sup>5</sup>; CN<sup>-</sup> is a strong field ligand giving a low-spin t<sub>2g</sub><sup>5</sup> arrangement with 1 unpaired electron. mu = sqrt(1(1+2)) = 1.73 BM.

Octahedralcoordination no. 6e.g. [Co(NH3)6]3+Tetrahedralcoordination no. 4e.g. [Ni(CO)4]Square Planarcoordination no. 4e.g. [Pt(NH3)2Cl2]

The three common coordination geometries: octahedral (6 ligands), tetrahedral (4 ligands), and square planar (4 ligands in one plane).

Concept context

Study of compounds where a central metal atom is bonded to surrounding ligands. Covers nomenclature, types of isomerism, bonding theories (VBT, CFT), and applications in medicine, photography, and industry.

Read the full Coordination Compounds notes →