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🧪 Chemistry  ·  Coordination Compounds  ·  NEET & JEE

The shape of [Ni(CN)4]2- is:

Answer: Square planar.

  • A Square planar
  • B Tetrahedral
  • C Octahedral
  • D Linear

Correct answer: A. Square planar

Explanation: [Ni(CN)4]2- is square planar; CN- is a strong field ligand that forces dsp<sup>2</sup> hybridisation on Ni<sup>2+</sup> (d<sup>8</sup> configuration).

Octahedralcoordination no. 6e.g. [Co(NH3)6]3+Tetrahedralcoordination no. 4e.g. [Ni(CO)4]Square Planarcoordination no. 4e.g. [Pt(NH3)2Cl2]

The three common coordination geometries: octahedral (6 ligands), tetrahedral (4 ligands), and square planar (4 ligands in one plane).

Concept context

Study of compounds where a central metal atom is bonded to surrounding ligands. Covers nomenclature, types of isomerism, bonding theories (VBT, CFT), and applications in medicine, photography, and industry.

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