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🧪 Chemistry  ·  Coordination Compounds  ·  NEET & JEE

The primary valence in Werner's theory corresponds to:

Answer: Oxidation state (ionisable valence).

  • A Oxidation state (ionisable valence)
  • B The coordination number, which Werner instead termed secondary valence
  • C A separate secondary valence distinct from the primary valence
  • D Simply the total number of ligands bound to the metal centre

Correct answer: A. Oxidation state (ionisable valence)

Explanation: Werner's primary valence = oxidation state (charged bonds satisfying electrovalence). Secondary valence = coordination number.

Octahedralcoordination no. 6e.g. [Co(NH3)6]3+Tetrahedralcoordination no. 4e.g. [Ni(CO)4]Square Planarcoordination no. 4e.g. [Pt(NH3)2Cl2]

The three common coordination geometries: octahedral (6 ligands), tetrahedral (4 ligands), and square planar (4 ligands in one plane).

Concept context

Study of compounds where a central metal atom is bonded to surrounding ligands. Covers nomenclature, types of isomerism, bonding theories (VBT, CFT), and applications in medicine, photography, and industry.

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