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🧪 Chemistry  ·  Coordination Compounds  ·  NEET & JEE

The effective atomic number (EAN) of iron in [Fe(CN)<sub>6</sub>]<sup>4-</sup> is:

Answer: 36.

  • A 34
  • B 36
  • C 35
  • D 38

Correct answer: B. 36

Explanation: Fe<sup>2+</sup> has 24 electrons; six CN<sup>-</sup> donate 6 x 2 = 12 electrons. EAN = 24 + 12 = 36, equal to krypton.

Octahedralcoordination no. 6e.g. [Co(NH3)6]3+Tetrahedralcoordination no. 4e.g. [Ni(CO)4]Square Planarcoordination no. 4e.g. [Pt(NH3)2Cl2]

The three common coordination geometries: octahedral (6 ligands), tetrahedral (4 ligands), and square planar (4 ligands in one plane).

Concept context

Study of compounds where a central metal atom is bonded to surrounding ligands. Covers nomenclature, types of isomerism, bonding theories (VBT, CFT), and applications in medicine, photography, and industry.

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