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🧪 Chemistry  ·  Coordination Compounds  ·  NEET & JEE

In the complex [Co(NH₃)₆]³⁺, cobalt(III) with the strong-field NH₃ ligand uses the hybridisation:

Answer: d²sp³ inner orbital.

  • A sp³ tetrahedral
  • B dsp² square planar
  • C sp³d² outer orbital
  • D d²sp³ inner orbital

Correct answer: D. d²sp³ inner orbital

Explanation: NH₃ is a strong-field ligand, so Co³⁺ (d⁶) pairs its electrons and uses inner (n−1)d orbitals: d²sp³, giving a low-spin octahedral complex.

Octahedralcoordination no. 6e.g. [Co(NH3)6]3+Tetrahedralcoordination no. 4e.g. [Ni(CO)4]Square Planarcoordination no. 4e.g. [Pt(NH3)2Cl2]

The three common coordination geometries: octahedral (6 ligands), tetrahedral (4 ligands), and square planar (4 ligands in one plane).

Concept context

Study of compounds where a central metal atom is bonded to surrounding ligands. Covers nomenclature, types of isomerism, bonding theories (VBT, CFT), and applications in medicine, photography, and industry.

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