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🧪 Chemistry  ·  Coordination Compounds  ·  NEET & JEE

In an octahedral complex MA3B3, the two geometrical isomers are:

Answer: Facial (fac) and meridional (mer).

  • A Facial (fac) and meridional (mer)
  • B Cis and trans
  • C Clockwise and anticlockwise
  • D Alpha and beta

Correct answer: A. Facial (fac) and meridional (mer)

Explanation: In MA3B3 octahedral: fac isomer has A ligands on one face of the octahedron; mer has A ligands in a plane through the centre.

Octahedralcoordination no. 6e.g. [Co(NH3)6]3+Tetrahedralcoordination no. 4e.g. [Ni(CO)4]Square Planarcoordination no. 4e.g. [Pt(NH3)2Cl2]

The three common coordination geometries: octahedral (6 ligands), tetrahedral (4 ligands), and square planar (4 ligands in one plane).

Concept context

Study of compounds where a central metal atom is bonded to surrounding ligands. Covers nomenclature, types of isomerism, bonding theories (VBT, CFT), and applications in medicine, photography, and industry.

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