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🧪 Chemistry  ·  Coordination Compounds  ·  NEET & JEE

Geometrical isomerism (cis-trans) is possible in square planar complexes with:

Answer: MA2B2 type (e.g., [Pt(NH 3 ) 2 Cl 2 ]).

  • A MA2B2 type (e.g., [Pt(NH<sub>3</sub>)<sub>2</sub>Cl<sub>2</sub>])
  • B MA4 type complexes, which show no geometric isomerism in square planar geometry
  • C MA6 type complexes, which are not square planar at all
  • D MA2 type complexes, which have too few ligands to show cis-trans isomerism

Correct answer: A. MA2B2 type (e.g., [Pt(NH<sub>3</sub>)<sub>2</sub>Cl<sub>2</sub>])

Explanation: Square planar MA2B2 complexes can have A and B groups either adjacent (cis) or diagonal (trans), giving two isomers.

Octahedralcoordination no. 6e.g. [Co(NH3)6]3+Tetrahedralcoordination no. 4e.g. [Ni(CO)4]Square Planarcoordination no. 4e.g. [Pt(NH3)2Cl2]

The three common coordination geometries: octahedral (6 ligands), tetrahedral (4 ligands), and square planar (4 ligands in one plane).

Concept context

Study of compounds where a central metal atom is bonded to surrounding ligands. Covers nomenclature, types of isomerism, bonding theories (VBT, CFT), and applications in medicine, photography, and industry.

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