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🧪 Chemistry  ·  Coordination Compounds  ·  NEET & JEE

Electron pairing to give a low-spin octahedral complex occurs when:

Answer: Delta o exceeds the pairing energy P.

  • A the pairing energy P exceeds Delta<sub>o</sub>
  • B Delta<sub>o</sub> exceeds the pairing energy P
  • C the ligand is a weak field ligand
  • D the metal ion is in a low oxidation state

Correct answer: B. Delta<sub>o</sub> exceeds the pairing energy P

Explanation: When the crystal field splitting Delta<sub>o</sub> is greater than the pairing energy P (strong field ligands), electrons pair in t<sub>2g</sub> rather than occupy e<sub>g</sub>, giving a low-spin complex.

Octahedralcoordination no. 6e.g. [Co(NH3)6]3+Tetrahedralcoordination no. 4e.g. [Ni(CO)4]Square Planarcoordination no. 4e.g. [Pt(NH3)2Cl2]

The three common coordination geometries: octahedral (6 ligands), tetrahedral (4 ligands), and square planar (4 ligands in one plane).

Concept context

Study of compounds where a central metal atom is bonded to surrounding ligands. Covers nomenclature, types of isomerism, bonding theories (VBT, CFT), and applications in medicine, photography, and industry.

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