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🧪 Chemistry  ·  Coordination Compounds  ·  NEET & JEE

Coordination isomers differ by:

Answer: Exchange of ligands between two complex centres in a compound with both + and - complex ions.

  • A Exchange of ligands between two complex centres in a compound with both + and - complex ions
  • B The oxidation state formally assigned to each central metal ion present in the salt
  • C The total number of ligands individually attached to each of the two metal centres
  • D Geometry alone, while keeping an identical ligand distribution shared between centres

Correct answer: A. Exchange of ligands between two complex centres in a compound with both + and - complex ions

Explanation: Coordination isomers: in a compound with two complex ions, ligands redistribute between the cationic and anionic complex. E.g., [Co(en)3][Cr(CN)6] vs [Cr(en)3][Co(CN)6].

Octahedralcoordination no. 6e.g. [Co(NH3)6]3+Tetrahedralcoordination no. 4e.g. [Ni(CO)4]Square Planarcoordination no. 4e.g. [Pt(NH3)2Cl2]

The three common coordination geometries: octahedral (6 ligands), tetrahedral (4 ligands), and square planar (4 ligands in one plane).

Concept context

Study of compounds where a central metal atom is bonded to surrounding ligands. Covers nomenclature, types of isomerism, bonding theories (VBT, CFT), and applications in medicine, photography, and industry.

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