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🧪 Chemistry  ·  Classification of Elements and Periodicity in Properties  ·  NEET & JEE

The second electron affinity of oxygen is endothermic (+744 kJ/mol) because:

Answer: Adding an electron to O- (a negative ion) requires energy to overcome repulsion.

  • A Adding an electron to O- (a negative ion) requires energy to overcome repulsion
  • B Oxygen's atomic radius is generally too small to accept another electron in typical laboratory settings
  • C Oxygen has an unusually low electronegativity for its period under usual circumstances
  • D The process instead forms an unstable O<sup>3-</sup> trianion intermediate according to most researchers

Correct answer: A. Adding an electron to O- (a negative ion) requires energy to overcome repulsion

Explanation: The first EA is exothermic (neutral O gains e-), but the second EA is endothermic because adding e- to an already negative O- requires overcoming electrostatic repulsion.

The complete modern periodic table showing all 118 elements with atomic number, symbol, and atomic mass, color-coded by element category

The complete modern periodic table (118 elements). Image: Cepheus et al., Public Domain, via Wikimedia Commons.

Concept context

The periodic table organises all 118 elements by atomic number and similar properties. Study periodic trends like atomic radius, ionization energy, and electronegativity, and learn how an element's position predicts its behaviour.

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