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🧪 Chemistry  ·  Classification of Elements and Periodicity in Properties  ·  NEET & JEE

Ionisation energy of sulfur (S) is lower than phosphorus (P) even though S has higher atomic number. This is because:

Answer: Phosphorus has a half-filled 3p subshell (extra stability).

  • A Phosphorus has a half-filled 3p subshell (extra stability)
  • B Sulfur simply has more total electrons than phosphorus
  • C Phosphorus has a lower nuclear charge than sulfur
  • D Sulfur has a noticeably larger atomic radius than phosphorus

Correct answer: A. Phosphorus has a half-filled 3p subshell (extra stability)

Explanation: Phosphorus has a half-filled 3p<sup>3</sup> configuration, which is extra stable; pairing in S's 3p<sup>4</sup> makes one electron easier to remove.

The complete modern periodic table showing all 118 elements with atomic number, symbol, and atomic mass, color-coded by element category

The complete modern periodic table (118 elements). Image: Cepheus et al., Public Domain, via Wikimedia Commons.

Concept context

The periodic table organises all 118 elements by atomic number and similar properties. Study periodic trends like atomic radius, ionization energy, and electronegativity, and learn how an element's position predicts its behaviour.

Read the full Classification of Elements and Periodicity in Properties notes →