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🧪 Chemistry  ·  Chemical Bonding and Molecular Structure  ·  NEET & JEE

In a double bond, one bond is sigma and one is pi. The pi bond is WEAKER than the sigma bond because:

Answer: Lateral p orbital overlap is less effective than head-on axial overlap.

  • A Lateral p orbital overlap is less effective than head-on axial overlap
  • B Pi bonds generally span a greater bond length than sigma bonds as frequently described
  • C Pi bonds contain fewer electrons than the corresponding sigma bond
  • D Sigma bonds usually occupy inherently lower energy orbitals in most textbook accounts

Correct answer: A. Lateral p orbital overlap is less effective than head-on axial overlap

Explanation: Pi bonds form by sideways (lateral) overlap of p orbitals, which is less efficient than the direct head-on overlap of sigma bonds.

Linear180 deg, e.g. CO2Trigonal Planar120 deg, e.g. BF3Tetrahedral109.5 deg, e.g. CH4Trigonal Bipyramidale.g. PCl5Octahedrale.g. SF6

VSEPR theory predicts molecular shape from the number of bonding and lone electron pairs around the central atom.

Concept context

Understand how atoms join to form molecules. Covers ionic and covalent bonding, VSEPR theory, hybridization (sp, sp², sp³), molecular orbital theory, bond polarity, and intermolecular forces like hydrogen bonding.

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