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🧪 Chemistry  ·  Chemical Bonding and Molecular Structure  ·  NEET & JEE

Hyperconjugation involves delocalisation of electrons from:

Answer: C-H sigma bond into an adjacent empty or pi orbital.

  • A C-H sigma bond into an adjacent empty or pi orbital
  • B A lone pair delocalising directly into an adjacent sigma bond
  • C A filled pi bond delocalising into an adjacent sigma* orbital
  • D Two separate lone pairs delocalising into each other

Correct answer: A. C-H sigma bond into an adjacent empty or pi orbital

Explanation: Hyperconjugation (no-bond resonance) occurs when electrons in a C-H sigma bond are delocalised into an adjacent vacant or pi orbital.

Linear180 deg, e.g. CO2Trigonal Planar120 deg, e.g. BF3Tetrahedral109.5 deg, e.g. CH4Trigonal Bipyramidale.g. PCl5Octahedrale.g. SF6

VSEPR theory predicts molecular shape from the number of bonding and lone electron pairs around the central atom.

Concept context

Understand how atoms join to form molecules. Covers ionic and covalent bonding, VSEPR theory, hybridization (sp, sp², sp³), molecular orbital theory, bond polarity, and intermolecular forces like hydrogen bonding.

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