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🧪 Chemistry  ·  Chemical Bonding and Molecular Structure  ·  NEET & JEE

Fajan's rules predict that a compound has more covalent character when:

Answer: The cation is small and highly charged, and the anion is large and highly charged.

  • A The cation is small and highly charged, and the anion is large and highly charged
  • B Both the cation and the anion happen to be of nearly identical ionic radius
  • C The compound has already been independently classified as purely ionic
  • D The surrounding reaction temperature is kept unusually high throughout

Correct answer: A. The cation is small and highly charged, and the anion is large and highly charged

Explanation: Fajan's rules: high charge density of the cation polarises the large anion, increasing covalent character.

Linear180 deg, e.g. CO2Trigonal Planar120 deg, e.g. BF3Tetrahedral109.5 deg, e.g. CH4Trigonal Bipyramidale.g. PCl5Octahedrale.g. SF6

VSEPR theory predicts molecular shape from the number of bonding and lone electron pairs around the central atom.

Concept context

Understand how atoms join to form molecules. Covers ionic and covalent bonding, VSEPR theory, hybridization (sp, sp², sp³), molecular orbital theory, bond polarity, and intermolecular forces like hydrogen bonding.

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