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🧪 Chemistry  ·  Thermodynamics  ·  NEET & JEE

The heat change measured at constant volume is equal to the change in:

Answer: internal energy.

  • A the enthalpy
  • B internal energy
  • C the entropy
  • D the free energy

Correct answer: B. internal energy

Explanation: At constant volume no PV work is done, so q_v = ΔU.

P-V Diagram: Isothermal vs Adiabatic ExpansionVPIsothermal (T constant)Adiabatic (q=0)Adiabatic curve is steeper: no heat enters to cushion the pressure drop

Isothermal expansion follows a gentler curve (heat flows in to keep T constant) while adiabatic expansion drops in pressure more steeply (no heat exchange, so internal energy and temperature fall as the gas does work).

Concept context

Study energy changes in chemical reactions. Understand enthalpy, entropy, Gibbs free energy, and the laws of thermodynamics that decide whether a reaction will occur spontaneously or not.

Read the full Thermodynamics notes →