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🧪 Chemistry  ·  States of Matter  ·  NEET & JEE

The van der Waals constant "b" is a correction for:

Answer: the finite volume of molecules.

  • A the attractive forces present
  • B the finite volume of molecules
  • C the average kinetic energy
  • D the absolute temperature

Correct answer: B. the finite volume of molecules

Explanation: The term nb corrects the volume for the finite size of the gas molecules themselves.

Graph of pressure versus volume for a fixed amount of gas at constant temperature: the curve falls steeply then flattens, a hyperbola showing pressure inversely proportional to volume.

Boyle's law: at constant temperature the pressure of a fixed mass of gas is inversely proportional to its volume (P ∝ 1/V), so the P–V plot is a hyperbola — halving the volume doubles the pressure. Image: Reginaprice2013, CC BY-SA 3.0, via Wikimedia Commons.

Concept context

Discover why gases expand to fill any container while liquids flow and solids hold their shape. Master the gas laws, the ideal gas equation, and the reasons real gases deviate from ideal behavior.

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