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🧪 Chemistry  ·  States of Matter  ·  NEET & JEE

Real gases deviate most from ideal behaviour under conditions of:

Answer: low temperature and high pressure.

  • A high temperature and low pressure
  • B low temperature and high pressure
  • C high temperature and high pressure
  • D standard temperature and pressure

Correct answer: B. low temperature and high pressure

Explanation: At low temperature and high pressure, molecules are close together and attractions and molecular volume become significant.

Graph of pressure versus volume for a fixed amount of gas at constant temperature: the curve falls steeply then flattens, a hyperbola showing pressure inversely proportional to volume.

Boyle's law: at constant temperature the pressure of a fixed mass of gas is inversely proportional to its volume (P ∝ 1/V), so the P–V plot is a hyperbola — halving the volume doubles the pressure. Image: Reginaprice2013, CC BY-SA 3.0, via Wikimedia Commons.

Concept context

Discover why gases expand to fill any container while liquids flow and solids hold their shape. Master the gas laws, the ideal gas equation, and the reasons real gases deviate from ideal behavior.

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