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🧪 Chemistry  ·  States of Matter  ·  NEET & JEE

A gas shows compressibility factor Z greater than 1 at very high pressure. This indicates that:

Answer: The gas is harder to compress than an ideal gas due to molecular volume effects.

  • A Attractive intermolecular forces dominate over repulsive forces at this pressure
  • B The gas compresses more easily than an ideal gas would at the same pressure
  • C The gas is harder to compress than an ideal gas due to molecular volume effects
  • D The gas has fully liquefied into a dense, incompressible liquid phase

Correct answer: C. The gas is harder to compress than an ideal gas due to molecular volume effects

Explanation: Z greater than 1 at high pressure shows the real volume is greater than ideal gas volume because molecular size effects dominate over attraction.

Graph of pressure versus volume for a fixed amount of gas at constant temperature: the curve falls steeply then flattens, a hyperbola showing pressure inversely proportional to volume.

Boyle's law: at constant temperature the pressure of a fixed mass of gas is inversely proportional to its volume (P ∝ 1/V), so the P–V plot is a hyperbola — halving the volume doubles the pressure. Image: Reginaprice2013, CC BY-SA 3.0, via Wikimedia Commons.

Concept context

Discover why gases expand to fill any container while liquids flow and solids hold their shape. Master the gas laws, the ideal gas equation, and the reasons real gases deviate from ideal behavior.

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