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🧪 Chemistry  ·  Solutions  ·  NEET & JEE

Abnormally high or low molar masses obtained from colligative measurements are caused by:

Answer: dissociation or association of the solute.

  • A an unusually high temperature applied
  • B dissociation or association of the solute
  • C an unusually high external pressure
  • D the presence of an active catalyst

Correct answer: B. dissociation or association of the solute

Explanation: When the solute dissociates or associates, the actual particle count differs from that assumed, giving an abnormal molar mass.

Vapour Pressure: Pure Solvent vs SolutionTVapour PPure solventSolution (lower VP)ΔTfTf(soln)Tf(pure)Dissolved solute lowers vapour pressure at every temperature, shifting Tf down and Tb up

Adding a non-volatile solute lowers the solvent's vapour pressure at every temperature, which is the root cause behind all four colligative properties: it shifts the freezing point down and the boiling point up.

Concept context

Learn how substances dissolve and form mixtures. Covers concentration terms, colligative properties (boiling point elevation, freezing point depression, osmotic pressure), and ideal vs non-ideal solution behaviour.

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