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🧪 Chemistry  ·  Redox Reactions  ·  NEET & JEE

The comproportionation reaction (reverse of disproportionation) has the general form: A(higher OS) + A(lower OS) → A(intermediate OS). Which of the following is an example?

Answer: Cu 2+ + Cu → 2Cu+.

  • A 2H<sub>2</sub>O<sub>2</sub> → 2H<sub>2</sub>O + O<sub>2</sub>
  • B Cu<sup>2+</sup> + Cu → 2Cu+
  • C Cl<sub>2</sub> + 2NaOH → NaCl + NaOCl + H<sub>2</sub>O
  • D 2MnO<sub>4</sub><sup>-</sup> + 5H<sub>2</sub>C<sub>2</sub>O<sub>4</sub> → 2Mn<sup>2+</sup> + 10CO<sub>2</sub> + 8H<sub>2</sub>O

Correct answer: B. Cu<sup>2+</sup> + Cu → 2Cu+

Explanation: Cu²⁺ (OS +2) + Cu (OS 0) → 2Cu⁺ (OS +1). The higher and lower oxidation state of the same element combine to give an intermediate oxidation state. This is comproportionation.

Electron Transfer: Zn + Cu²⁺ → Zn²⁺ + CuZnloses 2e⁻OXIDISED (Zn → Zn²⁺)2e⁻Cu²⁺gains 2e⁻REDUCED (Cu²⁺ → Cu)Zn = reducing agentCu²⁺ = oxidising agent

Electron transfer in a redox reaction: zinc loses electrons (oxidised, acts as reducing agent) and copper(II) ions gain those same electrons (reduced, acts as oxidising agent).

Concept context

Master electron transfer in chemistry: assign oxidation states, balance half-reactions, identify oxidising and reducing agents, and connect redox to everyday reactions.

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