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🧪 Chemistry  ·  Redox Reactions  ·  NEET & JEE

The comproportionation reaction (reverse of disproportionation) has the general form: A(higher OS) + A(lower OS) → A(intermediate OS). Which of the following is an example?

Answer: Cu2+ + Cu → 2Cu+.

  • A 2H2O2 → 2H2O + O2
  • B Cu2+ + Cu → 2Cu+
  • C Cl2 + 2NaOH → NaCl + NaOCl + H2O
  • D 2MnO4- + 5H2C2O4 → 2Mn2+ + 10CO2 + 8H2O

Correct answer: B. Cu2+ + Cu → 2Cu+

Explanation: Cu²⁺ (OS +2) + Cu (OS 0) → 2Cu⁺ (OS +1). The higher and lower oxidation state of the same element combine to give an intermediate oxidation state. This is comproportionation.

Electron Transfer: Zn + Cu²⁺ → Zn²⁺ + CuZnloses 2e⁻OXIDISED (Zn → Zn²⁺)2e⁻Cu²⁺gains 2e⁻REDUCED (Cu²⁺ → Cu)Zn = reducing agentCu²⁺ = oxidising agent

Electron transfer in a redox reaction: zinc loses electrons (oxidised, acts as reducing agent) and copper(II) ions gain those same electrons (reduced, acts as oxidising agent).

Concept context

Master electron transfer in chemistry: assign oxidation states, balance half-reactions, identify oxidising and reducing agents, and connect redox to everyday reactions.

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