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Balance the following redox reaction in acidic medium: MnO<sub>4</sub><sup>-</sup> + C<sub>2</sub>O<sub>4</sub><sup>2-</sup> → Mn<sup>2+</sup> + CO<sub>2</sub>. What are the stoichiometric coefficients (MnO<sub>4</sub><sup>-</sup> : C<sub>2</sub>O<sub>4</sub><sup>2-</sup>)?

Answer: 2 : 5.

  • A 1 : 1
  • B 2 : 5
  • C 5 : 2
  • D 3 : 5

Correct answer: B. 2 : 5

Explanation: MnO₄⁻ + 8H⁺ + 5e⁻ → Mn²⁺ + 4H₂O (reduction, 5e⁻ per Mn). C₂O₄²⁻ → 2CO₂ + 2e⁻ (oxidation, 2e⁻ per oxalate). LCM(5,2) = 10. Multiply: 2 MnO₄⁻ (10e⁻ gained) and 5 C₂O₄²⁻ (10e⁻ lost). Ratio = 2 : 5.

Electron Transfer: Zn + Cu²⁺ → Zn²⁺ + CuZnloses 2e⁻OXIDISED (Zn → Zn²⁺)2e⁻Cu²⁺gains 2e⁻REDUCED (Cu²⁺ → Cu)Zn = reducing agentCu²⁺ = oxidising agent

Electron transfer in a redox reaction: zinc loses electrons (oxidised, acts as reducing agent) and copper(II) ions gain those same electrons (reduced, acts as oxidising agent).

Concept context

Master electron transfer in chemistry: assign oxidation states, balance half-reactions, identify oxidising and reducing agents, and connect redox to everyday reactions.

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