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🧪 Chemistry  ·  Hydrogen  ·  NEET & JEE

In which reaction does H<sub>2</sub>O<sub>2</sub> act as an oxidising agent in acidic medium?

Answer: H 2 O 2 + 2Fe 2+ + 2H+ → 2Fe 3+ + 2H 2 O.

  • A H<sub>2</sub>O<sub>2</sub> + 2Fe<sup>2+</sup> + 2H+ → 2Fe<sup>3+</sup> + 2H<sub>2</sub>O
  • B 2H<sub>2</sub>O<sub>2</sub> → 2H<sub>2</sub>O + O<sub>2</sub> (decomposition)
  • C H<sub>2</sub>O<sub>2</sub> + 2KMnO<sub>4</sub> → products
  • D H<sub>2</sub>O<sub>2</sub> + Na<sub>2</sub>SO<sub>3</sub> → Na<sub>2</sub>SO<sub>4</sub> + H<sub>2</sub>O

Correct answer: A. H<sub>2</sub>O<sub>2</sub> + 2Fe<sup>2+</sup> + 2H+ → 2Fe<sup>3+</sup> + 2H<sub>2</sub>O

Explanation: H<sub>2</sub>O<sub>2</sub> oxidises Fe<sup>2+</sup> to Fe<sup>3+</sup> in the Fenton reaction; this demonstrates its oxidising role in acidic solution.

Hydrogen Bonding Network in WaterOHHOHHOHHOHHDashed green lines = hydrogen bonds (weaker than O-H covalent bonds)

Each water molecule's O-H bonds (covalent, solid) can hydrogen-bond (dashed) to neighbouring molecules, forming an extended network responsible for water's unusually high boiling point and density anomaly.

Concept context

The simplest and most abundant element in the universe. Study its unique position in the periodic table, isotopes (protium, deuterium, tritium), properties of water and hydrogen peroxide, and industrial uses.

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