75 free MCQs on Hydrogen with worked answers and explanations. The simplest and most abundant element in the universe. Study its unique position in the periodic table, isotopes (protium, deuterium, tritium), properties of water and hydrogen peroxide, and industrial uses.
Below are 75 practice questions on Hydrogen, sorted Easy → Hard. Tap “Show answer & explanation” under any question to check yourself. Want the full theory first? Read the Hydrogen notes.
Each water molecule's O-H bonds (covalent, solid) can hydrogen-bond (dashed) to neighbouring molecules, forming an extended network responsible for water's unusually high boiling point and density anomaly.
Easy - 25 questions
Q1.
Hydrogen resembles the halogens (Group 17) in which one of these respects?
A It is one electron short of a noble-gas shell
B It forms strongly basic oxides on combustion
C It has a very low ionisation enthalpy like them
D It exists as a liquid at room temperature
Show answer & explanation
Answer: A. It is one electron short of a noble-gas shell
Why: Like the halogens, hydrogen is one electron short of the nearest noble-gas configuration (He) and can gain an electron to form the hydride ion H<sup>-</sup>, so it is sometimes placed with Group 17.
Q2.
Which of the following is classified as an electron-deficient hydride?
A Methane, CH<sub>4</sub>
B Diborane, B<sub>2</sub>H<sub>6</sub>
C Water, H<sub>2</sub>O
D Ammonia, NH<sub>3</sub>
Show answer & explanation
Answer: B. Diborane, B<sub>2</sub>H<sub>6</sub>
Why: Diborane B<sub>2</sub>H<sub>6</sub> has fewer electrons than needed for normal covalent bonds, making it an electron-deficient hydride of the Group 13 element boron.
Q3.
Which element has the greatest tendency to form covalent molecular hydrides?
A Sodium, a reactive s-block metal
B Calcium, an alkaline earth metal
C Carbon, a p-block non-metal
D Potassium, a soft alkali metal
Show answer & explanation
Answer: C. Carbon, a p-block non-metal
Why: p-block non-metals such as carbon form covalent molecular hydrides; s-block metals like Na, K and Ca form ionic (saline) hydrides instead.
Q4.
Why is dihydrogen relatively unreactive at ordinary room temperature?
A It spontaneously ionises to give H<sup>+</sup>
B Its molecules are strongly polar
C It has a very high electron affinity
D Its H–H bond enthalpy is very high
Show answer & explanation
Answer: D. Its H–H bond enthalpy is very high
Why: The strong H–H bond (about 435.9 kJ mol<sup>-1</sup>) must be broken for a reaction, so dihydrogen is comparatively inert unless heated or a catalyst is used.
Q5.
Hydrogen peroxide is stored in wax-lined bottles kept in the dark because:
A Light and rough surfaces catalyse its decomposition
B It is very volatile and evaporates fast
C It reacts violently with the silica in glass
D It freezes very readily near room temperature
Show answer & explanation
Answer: A. Light and rough surfaces catalyse its decomposition
Why: H<sub>2</sub>O<sub>2</sub> decomposes to water and oxygen; light, heat and ions present in ordinary glass catalyse this, so it is kept in dark wax-lined or plastic containers.
Q6.
What is the atomic number of hydrogen?
A 1
B 2
C 6
D 8
Show answer & explanation
Answer: A. 1
Why: Hydrogen has atomic number 1 (one proton) and is the lightest and most abundant element in the universe.
Q7.
How many isotopes does hydrogen have?
A 3 (protium, deuterium, tritium)
B 2, counting only protium and deuterium
C 4, including a hypothetical quadrium isotope
D 1, since hydrogen has no other known isotopes
Show answer & explanation
Answer: A. 3 (protium, deuterium, tritium)
Why: Hydrogen has three isotopes: protium (1H, no neutrons), deuterium (2H, 1 neutron), and tritium (3H, 2 neutrons, radioactive).
Q8.
Heavy water is:
A D<sub>2</sub>O (deuterium oxide)
B H<sub>2</sub>O<sub>2</sub>
C H<sub>2</sub>O with salts
D Tritium water
Show answer & explanation
Answer: A. D<sub>2</sub>O (deuterium oxide)
Why: Heavy water is D<sub>2</sub>O, where normal hydrogen is replaced by deuterium (2H).
Q9.
Hydrogen gas is produced in the laboratory by:
A Reaction of zinc with dilute sulfuric acid
B Simple electrolysis of pure water without any added electrolyte
C Direct heating of water to its boiling point
D Mixing solid NaOH pellets with cold water
Show answer & explanation
Answer: A. Reaction of zinc with dilute sulfuric acid
Why: Zn + H<sub>2</sub>SO<sub>4</sub> (dil) → ZnSO<sub>4</sub> + H<sub>2</sub> is the common lab method to produce hydrogen gas.
Q10.
Which process is used industrially to produce hydrogen from natural gas?
A Steam reforming
B Haber process
C Contact process
D Hall process
Show answer & explanation
Answer: A. Steam reforming
Why: Steam reforming: CH<sub>4</sub> + H<sub>2</sub>O → CO + 3H<sub>2</sub> (catalysed by Ni at high temperature) is the main industrial route.
What is the oxidation state of hydrogen in metal hydrides (e.g., NaH)?
A -1
B 0
C +1
D +2
Show answer & explanation
Answer: A. -1
Why: In metal hydrides, hydrogen exists as H- (hydride ion) with oxidation state -1.
Q13.
What is the oxidation state of hydrogen in compounds with non-metals (e.g., HCl)?
A +1
B 0
C -1
D +2
Show answer & explanation
Answer: A. +1
Why: In most compounds with non-metals, hydrogen has oxidation state +1.
Q14.
Hydrogen peroxide (H<sub>2</sub>O<sub>2</sub>) is a powerful:
A Oxidising agent
B Reducing agent only
C Acid
D Base
Show answer & explanation
Answer: A. Oxidising agent
Why: H<sub>2</sub>O<sub>2</sub> is primarily an oxidising agent; it can also act as a reducing agent in reactions with stronger oxidants.
Q15.
The purest form of water is:
A Distilled water
B Rain water
C Tap water
D Sea water
Show answer & explanation
Answer: A. Distilled water
Why: Distilled water has most dissolved impurities removed and is considered very pure for laboratory use.
Q16.
Hard water contains dissolved salts of:
A Calcium and magnesium
B Sodium and potassium
C Iron and copper
D Sodium chloride only
Show answer & explanation
Answer: A. Calcium and magnesium
Why: Hard water contains dissolved Ca<sup>2+</sup> and Mg<sup>2+</sup> salts (bicarbonates, sulfates, chlorides) that prevent lathering with soap.
Q17.
Temporary hardness of water is caused by:
A Ca(HCO<sub>3</sub>)<sub>2</sub> and Mg(HCO<sub>3</sub>)<sub>2</sub>
B CaSO<sub>4</sub> and MgSO<sub>4</sub> as generally observed
C CaCl<sub>2</sub> and MgCl<sub>2</sub> in typical laboratory settings
D NaCl under usual circumstances
Show answer & explanation
Answer: A. Ca(HCO<sub>3</sub>)<sub>2</sub> and Mg(HCO<sub>3</sub>)<sub>2</sub>
Why: Temporary hardness is caused by bicarbonates of calcium and magnesium, which can be removed by boiling.
Q18.
Permanent hardness of water is caused by:
A CaSO<sub>4</sub>, MgSO<sub>4</sub>, CaCl<sub>2</sub>, MgCl<sub>2</sub>
B Ca(HCO<sub>3</sub>)<sub>2</sub> according to most researchers
C Carbonate salts in the majority of cases studied
D NaHCO<sub>3</sub> as widely reported
Show answer & explanation
Answer: A. CaSO<sub>4</sub>, MgSO<sub>4</sub>, CaCl<sub>2</sub>, MgCl<sub>2</sub>
Why: Permanent hardness is due to sulfates and chlorides of Ca and Mg, which cannot be removed by boiling.
Q19.
Which method removes both temporary and permanent hardness?
A Ion exchange method
B Boiling
C Distillation of a small amount
D Addition of Na<sub>2</sub>CO<sub>3</sub>
Show answer & explanation
Answer: A. Ion exchange method
Why: Ion exchange resins replace Ca<sup>2+</sup> and Mg<sup>2+</sup> ions with Na+ (or H+), removing all types of hardness.
Q20.
H<sub>2</sub>O<sub>2</sub> decomposes on exposure to light to give:
A H<sub>2</sub>O and O<sub>2</sub>
B H<sub>2</sub> and O<sub>2</sub>
C H<sub>2</sub> and H<sub>2</sub>O
D HO<sub>2</sub> and H
Show answer & explanation
Answer: A. H<sub>2</sub>O and O<sub>2</sub>
Why: 2H<sub>2</sub>O<sub>2</sub> → 2H<sub>2</sub>O + O<sub>2</sub>; this is why H<sub>2</sub>O<sub>2</sub> is stored in dark/coloured bottles.
Q21.
Hydrogen is used as a fuel because:
A It has very high calorific value and burns cleanly
B It is currently the cheapest fuel available on the market
C It exists as a stable solid at room temperature
D It is classified as a non-flammable gas
Show answer & explanation
Answer: A. It has very high calorific value and burns cleanly
Why: Hydrogen has the highest energy density per unit mass and produces only water on combustion.
Q22.
Which type of hydride is formed by alkali metals?
A Ionic (saline) hydrides
B Covalent hydrides
C Interstitial hydrides
D Polymeric hydrides
Show answer & explanation
Answer: A. Ionic (saline) hydrides
Why: Alkali metals (Group 1) react with H<sub>2</sub> to form ionic hydrides containing H- ions (e.g., NaH, LiH).
Q23.
Water has an unusually high boiling point (100°C) due to:
A Extensive hydrogen bonding
B High atomic mass
C Ionic character
D Large molecular size
Show answer & explanation
Answer: A. Extensive hydrogen bonding
Why: Water molecules form strong intermolecular hydrogen bonds, requiring extra energy to vaporise.
Q24.
The dihydrogen molecule (H<sub>2</sub>) has a bond order of:
A 1
B 2
C 3
D 0
Show answer & explanation
Answer: A. 1
Why: H<sub>2</sub> has two electrons in the bonding MO and none in antibonding: bond order = (2-0)/2 = 1.
Q25.
Which of the following is NOT an isotope of hydrogen?
A Helium, the noble gas with two protons and two neutrons in its common isotope
B Protium, the most abundant isotope with one proton and no neutrons in standard practice
C Deuterium, the isotope with one proton and one neutron under most conditions encountered
D Tritium, the radioactive isotope with one proton and two neutrons as frequently observed in practice
Show answer & explanation
Answer: A. Helium, the noble gas with two protons and two neutrons in its common isotope
Why: Helium (He) is a separate element. The three isotopes of hydrogen are protium (H), deuterium (D), and tritium (T).
Medium - 25 questions
Q26.
In 2MnO<sub>4</sub><sup>-</sup> + 5H<sub>2</sub>O<sub>2</sub> + 6H<sup>+</sup> → 2Mn<sup>2+</sup> + 5O<sub>2</sub> + 8H<sub>2</sub>O, hydrogen peroxide behaves as a:
A Oxidising agent, its oxygen going -1 to -2
B Reducing agent, its oxygen going from -1 to 0
C Catalyst that stays chemically unchanged
D Simple dehydrating agent in this medium
Show answer & explanation
Answer: B. Reducing agent, its oxygen going from -1 to 0
Why: Here H<sub>2</sub>O<sub>2</sub> reduces MnO<sub>4</sub><sup>-</sup> to Mn<sup>2+</sup>; its own oxygen is oxidised from -1 to 0 (O<sub>2</sub>), so it acts as a reducing agent.
Q27.
A hydrogen peroxide sample marked '10 volume' means that:
A It contains 10 g of H<sub>2</sub>O<sub>2</sub> per litre
B It is a 10 molar solution of H<sub>2</sub>O<sub>2</sub>
C 1 mL gives 10 mL of O<sub>2</sub> at STP on decay
D It is exactly 10% H<sub>2</sub>O<sub>2</sub> by mass
Show answer & explanation
Answer: C. 1 mL gives 10 mL of O<sub>2</sub> at STP on decay
Why: Volume strength is the volume of O<sub>2</sub> (at STP) liberated per unit volume of solution; '10 volume' gives 10 mL of O<sub>2</sub> per mL of the solution.
Q28.
The catalytic reaction CO + 2H<sub>2</sub> → CH<sub>3</sub>OH is used industrially to manufacture:
A Ethylene glycol
B Formaldehyde
C Acetic acid
D Methanol
Show answer & explanation
Answer: D. Methanol
Why: Catalytic combination of CO and H<sub>2</sub> (synthesis gas) yields methanol, an important industrial hydrogenation of carbon monoxide.
Q29.
Assertion: The two O–H bonds of H<sub>2</sub>O<sub>2</sub> do not lie in one plane. Reason: It has an open-book (non-planar) structure.
A Both true and the reason explains it
B Both true but reason does not explain it
C Assertion false but reason is true
D Assertion true but the reason is false
Show answer & explanation
Answer: A. Both true and the reason explains it
Why: H<sub>2</sub>O<sub>2</sub> has a non-planar open-book structure in which the two O–H bonds lie in different planes, so the reason correctly explains the assertion.
Q30.
Which statement about the three isotopes of hydrogen is correct?
A They differ in their number of protons
B Protium, deuterium, tritium have 0,1,2 neutrons
C They each contain the same neutron count
D Tritium is the most abundant in nature
Show answer & explanation
Answer: B. Protium, deuterium, tritium have 0,1,2 neutrons
Why: Protium, deuterium and tritium all have one proton but 0, 1 and 2 neutrons respectively; protium is by far the most abundant isotope.
Q31.
The water-gas shift reaction is:
A CO + H<sub>2</sub>O → CO<sub>2</sub> + H<sub>2</sub>
B CH<sub>4</sub> + H<sub>2</sub>O → CO + H<sub>2</sub>
C C + H<sub>2</sub>O → CO + H<sub>2</sub>
D 2H<sub>2</sub>O → 2H<sub>2</sub> + O<sub>2</sub>
Show answer & explanation
Answer: A. CO + H<sub>2</sub>O → CO<sub>2</sub> + H<sub>2</sub>
Why: The water-gas shift reaction (CO + H<sub>2</sub>O → CO<sub>2</sub> + H<sub>2</sub>) increases H<sub>2</sub> yield from syngas by converting CO with steam.
Q32.
Which compound acts as both oxidising and reducing agent?
A H<sub>2</sub>O<sub>2</sub>
B HCl
C H<sub>2</sub>SO<sub>4</sub>
D HNO<sub>3</sub>
Show answer & explanation
Answer: A. H<sub>2</sub>O<sub>2</sub>
Why: H<sub>2</sub>O<sub>2</sub> can oxidise (it gains electrons) or reduce (it donates electrons to a stronger oxidant like KMnO<sub>4</sub>).
Q33.
The concentration of H<sub>2</sub>O<sub>2</sub> is expressed in:
A Volume strength (V10, V20) based on O<sub>2</sub> liberated
B The fixed molar mass value of the H<sub>2</sub>O<sub>2</sub> molecule
C The measured pH of the aqueous solution
D The bulk density of the solution alone
Show answer & explanation
Answer: A. Volume strength (V10, V20) based on O<sub>2</sub> liberated
Why: '10 volume' H<sub>2</sub>O<sub>2</sub> means 1 L of the solution liberates 10 L of O<sub>2</sub> at STP.
Q34.
Bleaching by H<sub>2</sub>O<sub>2</sub> is due to its:
A Oxidising action (releases nascent oxygen)
B Reducing action that decolourises dyes by hydrogenation
C Its mildly acidic nature lowering the solution's pH
D Its mildly alkaline nature raising the solution's pH
Show answer & explanation
Answer: A. Oxidising action (releases nascent oxygen)
Why: H<sub>2</sub>O<sub>2</sub> bleaches by releasing nascent oxygen that oxidises coloured compounds, destroying chromophore groups.
Q35.
The reaction H<sub>2</sub>O<sub>2</sub> + KI → I<sub>2</sub> + KOH + H<sub>2</sub>O demonstrates H<sub>2</sub>O<sub>2</sub> acting as:
A Oxidising agent (oxidises I- to I<sub>2</sub>)
B Reducing agent in the majority of cases studied
C Both oxidant and reductant as widely reported
D Neutral catalyst in standard practice
Show answer & explanation
Answer: A. Oxidising agent (oxidises I- to I<sub>2</sub>)
Why: H<sub>2</sub>O<sub>2</sub> oxidises I- (from KI) to I<sub>2</sub>, itself being reduced to water. This is its oxidising action.
Q36.
Why does ice float on water?
A Water at 4°C is densest; ice has open hydrogen-bonded lattice making it less dense than liquid water
B Solid ice molecules acquire a higher effective molecular weight than liquid water molecules under most conditions encountered
C Liquid water expands mainly very slightly in volume as it approaches 0°C as frequently observed in practice
D Ice is held together largely by weak van der Waals forces rather than hydrogen bonds in many documented cases
Show answer & explanation
Answer: A. Water at 4°C is densest; ice has open hydrogen-bonded lattice making it less dense than liquid water
Why: In ice, hydrogen bonds create an open tetrahedral lattice with more space between molecules than in liquid water, making ice less dense.
Q37.
The softening of water by Clark's method involves adding:
A Slaked lime Ca(OH)<sub>2</sub> to remove temporary hardness by precipitating CaCO<sub>3</sub>
B Washing soda (Na<sub>2</sub>CO<sub>3</sub>) to precipitate both temporary and permanent hardness
C A synthetic ion exchange resin that swaps Ca<sup>2+</sup> for Na+
D Alum, which coagulates suspended colloidal clay particles
Show answer & explanation
Answer: A. Slaked lime Ca(OH)<sub>2</sub> to remove temporary hardness by precipitating CaCO<sub>3</sub>
Why: Clark's method adds just enough lime to convert soluble bicarbonates to insoluble carbonates: Ca(HCO<sub>3</sub>)<sub>2</sub> + Ca(OH)<sub>2</sub> → 2CaCO<sub>3</sub> + 2H<sub>2</sub>O.
Q38.
The Permutit process uses which substance to soften water?
A Sodium aluminium silicate (zeolite/permutit) ion exchanger
B Activated charcoal that adsorbs dissolved calcium and magnesium ions
C A combined lime-and-soda treatment to precipitate both hardness types
D Simple distillation to vaporise and recondense the pure water
Show answer & explanation
Answer: A. Sodium aluminium silicate (zeolite/permutit) ion exchanger
Why: Permutit (zeolite, Na2Al2Si2O8) exchanges Na+ ions for Ca<sup>2+</sup> and Mg<sup>2+</sup> hardness ions, softening the water.
Q39.
Interstitial hydrides are formed by:
A d and f block transition metals (e.g., Pd, La) absorbing H<sub>2</sub> into lattice gaps
B Alkali metals forming stoichiometric ionic hydride salts according to conventional understanding
C Non-metals forming covalent molecular hydrides in routine practice overall
D Noble gases trapping hydrogen within clathrate cages in most cases under typical conditions
Show answer & explanation
Answer: A. d and f block transition metals (e.g., Pd, La) absorbing H<sub>2</sub> into lattice gaps
Why: Transition and lanthanide metals can absorb large amounts of H<sub>2</sub> into interstitial (gap) sites in their crystal lattices.
Q40.
The Haber process produces ammonia from:
A N<sub>2</sub> and H<sub>2</sub> (using Fe catalyst, high pressure, 400-500°C)
B N<sub>2</sub> and O<sub>2</sub> combined catalytically over a platinum gauze
C CH<sub>4</sub> and N<sub>2</sub> reacted directly at moderate pressure
D NH<sub>3</sub> itself recycled through a secondary catalytic loop
Show answer & explanation
Answer: A. N<sub>2</sub> and H<sub>2</sub> (using Fe catalyst, high pressure, 400-500°C)
Why: The Haber process: N<sub>2</sub> + 3H<sub>2</sub> ⇌ 2NH<sub>3</sub> (Fe catalyst, 150-200 atm, 400-500°C).
Q41.
What is syngas?
A A mixture of CO and H<sub>2</sub> produced from steam reforming of hydrocarbons
B Pure hydrogen gas obtained after fractional separation
C A mixture of methane and hydrogen used directly as a fuel blend
D A mixture of carbon dioxide and water vapour from combustion
Show answer & explanation
Answer: A. A mixture of CO and H<sub>2</sub> produced from steam reforming of hydrocarbons
Why: Synthesis gas (syngas) is a CO/H<sub>2</sub> mixture used as feedstock for methanol, ammonia, and Fischer-Tropsch fuels.
Q42.
The bond dissociation energy of H<sub>2</sub> is approximately:
A 436 kJ/mol
B 946 kJ/mol
C 240 kJ/mol
D 154 kJ/mol
Show answer & explanation
Answer: A. 436 kJ/mol
Why: The H-H bond dissociation energy is about 436 kJ/mol, relatively strong for a single bond.
Q43.
H<sub>2</sub>O<sub>2</sub> structure has a dihedral angle of about 111° in the gas phase because:
A Lone pair repulsion on oxygen atoms causes non-planar structure
B Both O-H bonds being chemically equivalent forces a planar geometry
C Ordinary water adopts an identical open-book dihedral structure
D The O-O linkage is actually a triple bond restricting rotation
Show answer & explanation
Answer: A. Lone pair repulsion on oxygen atoms causes non-planar structure
Why: Each oxygen in H<sub>2</sub>O<sub>2</sub> has two lone pairs; their repulsion twists the molecule into a non-planar 'book' structure.
Q44.
Nascent hydrogen is:
A Highly reactive atomic hydrogen formed in situ (not H<sub>2</sub> gas)
B Ordinary H<sub>2</sub> gas simply compressed to high pressure
C Deuterium gas generated by electrolysis of heavy water
D Pure protium gas isolated from natural hydrogen
Show answer & explanation
Answer: A. Highly reactive atomic hydrogen formed in situ (not H<sub>2</sub> gas)
Why: Nascent hydrogen is freshly generated atomic H (before it dimerises to H<sub>2</sub>), highly reactive due to unpaired electron.
Q45.
The ortho and para forms of dihydrogen differ in:
A Relative nuclear spin orientation of the two H nuclei (parallel vs antiparallel)
B The precisely measured H-H bond length within each form of the molecule
C The overall H-H bond dissociation energy required to break the molecule apart
D Their isotope composition, with the para form containing deuterium instead
Show answer & explanation
Answer: A. Relative nuclear spin orientation of the two H nuclei (parallel vs antiparallel)
Why: ortho-H<sub>2</sub> has parallel proton spins (triplet); para-H<sub>2</sub> has antiparallel spins (singlet). They have slightly different physical properties.
Q46.
H<sub>2</sub>O<sub>2</sub> acts as a reducing agent when it reacts with:
A Acidified KMnO<sub>4</sub> (a stronger oxidising agent)
B Iodide ion, which it oxidises to free iodine
C Fe<sup>2+</sup>, which it oxidises to Fe<sup>3+</sup>
D Cl<sub>2</sub> gas, which it reduces to chloride ion
Show answer & explanation
Answer: A. Acidified KMnO<sub>4</sub> (a stronger oxidising agent)
Why: When a stronger oxidant like acidified KMnO<sub>4</sub> reacts with H<sub>2</sub>O<sub>2</sub>, H<sub>2</sub>O<sub>2</sub> reduces MnO<sub>4</sub><sup>-</sup> by donating electrons: 2KMnO<sub>4</sub> + 5H<sub>2</sub>O<sub>2</sub> + 3H<sub>2</sub>SO<sub>4</sub> → 2MnSO<sub>4</sub> + 5O<sub>2</sub> + K<sub>2</sub>SO<sub>4</sub> + 8H<sub>2</sub>O.
Q47.
What percentage concentration is commercial H<sub>2</sub>O<sub>2</sub>?
A 3% (household), 30% (laboratory), 90%+ (industrial/rocket fuel)
B Usually supplied as pure 100% anhydrous liquid according to standard textbooks
C Fixed at 1% concentration for all commercial uses in general practice
D A single standard grade of 50% for every application as frequently described
Show answer & explanation
Answer: A. 3% (household), 30% (laboratory), 90%+ (industrial/rocket fuel)
Why: H<sub>2</sub>O<sub>2</sub> is sold in different concentrations: 3% (antiseptic), ~6-9% (hair bleaching), ~30% (lab), >90% (propellant).
Q48.
Calgon (sodium hexametaphosphate) softens water by:
A Forming soluble complexes with Ca<sup>2+</sup> and Mg<sup>2+</sup> ions (sequestration)
B Precipitating the calcium and magnesium ions as insoluble salts
C Exchanging the hardness ions for sodium ions on a resin bed
D Removing the hardness ions through simple distillation
Show answer & explanation
Answer: A. Forming soluble complexes with Ca<sup>2+</sup> and Mg<sup>2+</sup> ions (sequestration)
Why: Calgon sequestrates Ca<sup>2+</sup> and Mg<sup>2+</sup> by forming stable soluble complexes, preventing them from causing hardness.
Q49.
Liquid hydrogen is used as:
A Rocket fuel (cryogenic propellant)
B A substitute for drinking water in emergency supplies
C A high-temperature lubricant for industrial machinery
D A solid electrode material in galvanic cells
Show answer & explanation
Answer: A. Rocket fuel (cryogenic propellant)
Why: Liquid H<sub>2</sub> is used as cryogenic rocket fuel; it has the highest specific impulse of any chemical propellant.
Q50.
The dielectric constant of water (80) is much higher than most solvents because:
A Strong hydrogen bonding creates a highly ordered, polar medium that stabilises ions effectively
B Water generally has a higher physical density than most organic solvents in most textbook accounts
C Water molecules are unusually small compared to other solvent molecules during normal conditions
D Water is largely colourless and transparent to visible light as generally observed in typical laboratory settings
Show answer & explanation
Answer: A. Strong hydrogen bonding creates a highly ordered, polar medium that stabilises ions effectively
Why: The high dielectric constant of water means it strongly diminishes the electrostatic attraction between ions, making it an excellent ionic solvent.
Hard - 25 questions
Q51.
A hydrogen peroxide solution is labelled '20 volume'. Its percentage strength (w/v) is closest to:
A About 12 percent
B About 3 percent
C About 6 percent
D About 30 percent
Show answer & explanation
Answer: C. About 6 percent
Why: Percentage strength (w/v) = volume strength / 5.6, so 20/5.6 is roughly 3.6, giving about 6% H<sub>2</sub>O<sub>2</sub> expressed as grams per 100 mL.
Q52.
H<sub>2</sub>O<sub>2</sub> liberates iodine from acidified KI yet decolourises acidified KMnO<sub>4</sub>. This dual behaviour shows that it:
A Is a strong dehydrating agent only
B Always disproportionates in acid medium
C Is amphoteric exactly like water
D Can act as both oxidant and reductant
Show answer & explanation
Answer: D. Can act as both oxidant and reductant
Why: With KI it oxidises I<sup>-</sup> to I<sub>2</sub> (oxidant); with KMnO<sub>4</sub> it reduces Mn(VII) to Mn(II) (reductant). So H<sub>2</sub>O<sub>2</sub> is both an oxidising and a reducing agent.
Q53.
Deuterium oxide (D<sub>2</sub>O) is preferred over ordinary water as a moderator in nuclear reactors because:
A It slows neutrons while absorbing very few
B It is radioactive and sustains the reaction
C It has a far lower boiling point than water
D It strongly absorbs all thermal neutrons
Show answer & explanation
Answer: A. It slows neutrons while absorbing very few
Why: D<sub>2</sub>O moderates fast neutrons effectively while having a very low neutron-absorption cross-section, letting more neutrons sustain the chain reaction than ordinary water would.
Q54.
Reactions using deuterium generally proceed more slowly than with ordinary hydrogen because:
A Deuterium has a smaller atomic radius than protium
B D–X bonds have lower zero-point energy and break slower
C Deuterium compounds are ionic, not covalent
D Deuterium is far more electronegative than protium
Show answer & explanation
Answer: B. D–X bonds have lower zero-point energy and break slower
Why: Heavier deuterium gives a lower zero-point vibrational energy, so the D–X bond is effectively stronger and harder to break, slowing reactions in which that bond is broken (kinetic isotope effect).
Q55.
In C + H<sub>2</sub>O → CO + H<sub>2</sub> (steam on hot coke), the CO is removed to get pure dihydrogen by:
A Cooling the mixture below CO's boiling point
B Bubbling the gas through concentrated H<sub>2</sub>SO<sub>4</sub>
C Shifting CO with steam to CO<sub>2</sub>, then absorbing it
D Reacting the mixture directly with nitrogen gas
Show answer & explanation
Answer: C. Shifting CO with steam to CO<sub>2</sub>, then absorbing it
Why: In the water-gas shift CO + H<sub>2</sub>O reacts over iron chromate to give CO<sub>2</sub> + H<sub>2</sub>; the CO<sub>2</sub> is then scrubbed out under pressure, leaving pure dihydrogen.
Q56.
Tritium is used in which applications?
A Nuclear fusion fuel and luminescent markers (radioactive beta emitter)
B As a food preservative that extends shelf life through irradiation
C As a catalyst that accelerates hydrogenation reactions
D As an industrial solvent for non-polar organic extractions
Show answer & explanation
Answer: A. Nuclear fusion fuel and luminescent markers (radioactive beta emitter)
Why: Tritium (3H, T) is a radioactive hydrogen isotope used in thermonuclear fusion (D-T reaction) and in self-luminous watch dials and exit signs.
Q57.
The kinetic isotope effect (KIE) in chemistry means:
A Reactions with lighter isotopes (H) are faster than with heavier ones (D) because zero-point energy is higher for C-H
B All isotopes of a given element react at exactly the identical measured rate under most conditions encountered as frequently observed in practice
C Heavier isotopes such as deuterium consistently react faster than ordinary protium in many documented cases according to conventional understanding
D Changing the reaction temperature has little measurable effect on isotope-substituted reactions in routine practice
Show answer & explanation
Answer: A. Reactions with lighter isotopes (H) are faster than with heavier ones (D) because zero-point energy is higher for C-H
Why: Primary KIE: C-H bonds break faster than C-D bonds because C-H has higher zero-point energy, lower activation barrier.
Q58.
In the hydrogen economy concept, hydrogen is produced by:
A Electrolysis of water using renewable electricity (green hydrogen)
B Direct combustion of fossil fuels to liberate hydrogen gas
C Nuclear fission reactions that release hydrogen as a byproduct
D Microbial fermentation of organic waste material
Show answer & explanation
Answer: A. Electrolysis of water using renewable electricity (green hydrogen)
Why: Green hydrogen is produced by electrolysis of water powered by renewable energy (solar/wind), with zero carbon emissions.
Q59.
The anomalous properties of water compared to H<sub>2</sub>S, H<sub>2</sub>Se, H<sub>2</sub>Te are due to:
A Hydrogen bonding in water raises its boiling point far above the trend expected from molecular weight
B Water generally having a higher molecular weight than the other hydrides overall in most cases under typical conditions
C Water possessing significant ionic character in its O-H bonds according to standard textbooks in general practice
D Oxygen being a physically larger atom than sulfur, selenium, or tellurium as frequently described
Show answer & explanation
Answer: A. Hydrogen bonding in water raises its boiling point far above the trend expected from molecular weight
Why: Extrapolating the boiling points of H<sub>2</sub>S (-61°C), H<sub>2</sub>Se (-41°C), H<sub>2</sub>Te (-2°C) would predict H<sub>2</sub>O to boil at about -80°C. Hydrogen bonding raises it to 100°C.
Q60.
What is the role of palladium in hydrogen technology?
A Pd absorbs up to 900 times its own volume of H<sub>2</sub> (hydrogen storage) and catalyses hydrogenation
B Pd functions as a solid-state electrolyte conducting protons in fuel cells in most textbook accounts
C Pd forms a passivating oxide layer that prevents hydrogen oxidation largely during normal conditions
D Pd directly converts adsorbed H<sub>2</sub> gas into hydrogen peroxide as generally observed in typical laboratory settings
Show answer & explanation
Answer: A. Pd absorbs up to 900 times its own volume of H<sub>2</sub> (hydrogen storage) and catalyses hydrogenation
Why: Palladium uniquely dissolves large amounts of hydrogen into its lattice (forming PdHx), useful for purification and storage. It also catalyses hydrogenation reactions.
Q61.
The Born-Oppenheimer approximation applied to H<sub>2</sub><sup>+</sup> (simplest molecular ion) allows:
A Separation of nuclear and electronic motion to solve the Schrodinger equation exactly
B The simultaneous exact calculation of every molecular property at once under usual circumstances
C Complete neglect of quantum mechanical effects in the system according to most researchers
D A mainly classical mechanical treatment of the nuclei and electron in the majority of cases studied
Show answer & explanation
Answer: A. Separation of nuclear and electronic motion to solve the Schrodinger equation exactly
Why: H<sub>2</sub><sup>+</sup> has only one electron and two nuclei; with the Born-Oppenheimer approximation (fixed nuclei), it has an exact quantum mechanical solution.
Q62.
Why does H<sub>2</sub>O<sub>2</sub> have a higher boiling point (150°C) than water (100°C) despite having similar molecular weight?
A Both O atoms in H<sub>2</sub>O<sub>2</sub> form hydrogen bonds (more H-bond donors and acceptors per molecule)
B H<sub>2</sub>O<sub>2</sub> carries a significant degree of ionic character unlike water as widely reported
C H<sub>2</sub>O<sub>2</sub> molecules are generally much larger in physical size than water in standard practice
D H<sub>2</sub>O<sub>2</sub> lacks hydrogen bonding largely, relying mainly on dispersion forces under most conditions encountered
Show answer & explanation
Answer: A. Both O atoms in H<sub>2</sub>O<sub>2</sub> form hydrogen bonds (more H-bond donors and acceptors per molecule)
Why: H<sub>2</sub>O<sub>2</sub> has two O-H bonds and two oxygen lone pairs, enabling more extensive hydrogen bonding than water (one O, two O-H).
Q63.
What is 'hydrogen embrittlement'?
A Absorption of H<sub>2</sub> into metal lattice weakens metallic bonds, making the metal brittle and prone to cracking
B Hydrogen gas chemically reacting with the surface metal oxide layer to release water vapour as frequently observed in practice
C The bulk metal slowly dissolving away when largely immersed in liquid hydrogen peroxide in many documented cases
D The thermal softening effect produced by burning hydrogen gas nearby the metal surface according to conventional understanding
Show answer & explanation
Answer: A. Absorption of H<sub>2</sub> into metal lattice weakens metallic bonds, making the metal brittle and prone to cracking
Why: Hydrogen embrittlement occurs when atomic H diffuses into metal (e.g., steel), occupying voids and creating internal pressure that causes cracking.
Q64.
The para-hydrogen to ortho-hydrogen ratio at very low temperature approaches:
A 100% para-H<sub>2</sub> (para is lower energy at low T)
B 100% ortho-H<sub>2</sub>
C 50:50
D 75:25 ortho:para (room temperature equilibrium)
Show answer & explanation
Answer: A. 100% para-H<sub>2</sub> (para is lower energy at low T)
Why: para-H<sub>2</sub> (antiparallel nuclear spins) is the lower energy ground state; at near 0 K, essentially all H<sub>2</sub> is para form.
Q65.
Hydrogen fuel cells generate electricity by:
A Electrochemical oxidation of H<sub>2</sub> at anode, reduction of O<sub>2</sub> at cathode, water as byproduct
B Direct flame combustion of hydrogen gas inside the cell housing in routine practice
C Controlled nuclear fusion of hydrogen nuclei within the cell overall in most cases
D Thermal decomposition of hydrogen peroxide releasing oxygen gas under typical conditions
Show answer & explanation
Answer: A. Electrochemical oxidation of H<sub>2</sub> at anode, reduction of O<sub>2</sub> at cathode, water as byproduct
Why: In a PEM fuel cell: H<sub>2</sub> → 2H+ + 2e- (anode); O<sub>2</sub> + 4H+ + 4e- → 2H<sub>2</sub>O (cathode). Electrical energy from chemical energy without combustion.
Q66.
What is the significance of the 21 cm hydrogen emission line in astronomy?
A Spin-flip transition of electron in hydrogen; used to map galactic structure and detect neutral hydrogen clouds
B A strong ultraviolet absorption line produced by electronic excitation of bound hydrogen according to standard textbooks
C An energetic X-ray emission line produced by highly ionised hydrogen plasma in general practice as frequently described
D A mainly theoretical signal that remains permanently undetectable by any telescope in most textbook accounts
Show answer & explanation
Answer: A. Spin-flip transition of electron in hydrogen; used to map galactic structure and detect neutral hydrogen clouds
Why: The 21 cm line arises from the hyperfine transition in ground-state H (electron spin flip); it penetrates dust clouds, enabling radio mapping of galaxies.
Q67.
In which reaction does H<sub>2</sub>O<sub>2</sub> act as an oxidising agent in acidic medium?
A H<sub>2</sub>O<sub>2</sub> + 2Fe<sup>2+</sup> + 2H+ → 2Fe<sup>3+</sup> + 2H<sub>2</sub>O
B 2H<sub>2</sub>O<sub>2</sub> → 2H<sub>2</sub>O + O<sub>2</sub> (decomposition)
C H<sub>2</sub>O<sub>2</sub> + 2KMnO<sub>4</sub> → products
D H<sub>2</sub>O<sub>2</sub> + Na<sub>2</sub>SO<sub>3</sub> → Na<sub>2</sub>SO<sub>4</sub> + H<sub>2</sub>O
Why: H<sub>2</sub>O<sub>2</sub> oxidises Fe<sup>2+</sup> to Fe<sup>3+</sup> in the Fenton reaction; this demonstrates its oxidising role in acidic solution.
Q68.
Which condition favours formation of ionic hydrides over covalent hydrides?
A Low electronegativity and large size of the metal (strong electropositive character)
B An unusually high electronegativity of the metal element forming the hydride
C A particularly small atomic size of the non-metal that hydrogen bonds to
D Simply maintaining a high reaction temperature throughout the synthesis process
Show answer & explanation
Answer: A. Low electronegativity and large size of the metal (strong electropositive character)
Why: Ionic hydrides form when electropositive metals (Li, Na, Ca) transfer electrons completely to H; covalent hydrides form when electronegativity difference is small.
Q69.
The dielectric constant of heavy water (D<sub>2</sub>O) compared to ordinary water (H<sub>2</sub>O):
A Slightly lower (~78 vs 80) because D<sub>2</sub>O hydrogen bonds are slightly stronger making it less polarisable
B Noticeably higher than ordinary water mainly because of its greater molecular mass during normal conditions
C Exactly the same numerical value as ordinary water since both share identical polarity as generally observed
D Much lower, falling below 20, supposedly due to unusually weak deuterium bonding in typical laboratory settings
Show answer & explanation
Answer: A. Slightly lower (~78 vs 80) because D<sub>2</sub>O hydrogen bonds are slightly stronger making it less polarisable
Why: D<sub>2</sub>O has slightly stronger O-D...O hydrogen bonds than O-H...O, making the structure more rigid and slightly less polarisable.
Q70.
Hydrogen can exist as a metallic solid under extreme pressure. This was first observed in:
A Theoretical prediction; metallic H may exist in gas giant planet cores (Jupiter)
B Routine laboratory observation at ordinary atmospheric pressure under usual circumstances
C A stable solid state generally by cooling hydrogen to -200°C according to most researchers
D Mainly ever observed as an ordinary cryogenic liquid in the majority of cases studied
Show answer & explanation
Answer: A. Theoretical prediction; metallic H may exist in gas giant planet cores (Jupiter)
Why: Metallic hydrogen is predicted to form above 400 GPa; experimental evidence is disputed. It likely exists in Jupiter's core.
Q71.
The equilibrium 2H<sub>2</sub>O(l) ⇌ H<sub>3</sub>O<sup>+</sup>(aq) + OH-(aq) has Kw = 10-14 at 25°C. At 37°C (body temperature), Kw is:
A Greater than 10-14 (autodissociation is endothermic, favoured by higher T)
B Less than 10-14, since higher temperature suppresses autodissociation
C Unchanged at exactly 10-14 regardless of temperature
D Effectively zero, since water barely dissociates at body temperature
Show answer & explanation
Answer: A. Greater than 10-14 (autodissociation is endothermic, favoured by higher T)
Why: Water autoionisation is endothermic; increasing temperature shifts equilibrium right, increasing Kw above 10-14.
Q72.
In terms of bond enthalpy, the reaction H<sub>2</sub> → 2H requires approximately 436 kJ/mol. This means:
A H<sub>2</sub> is thermally stable; significant energy must be supplied to create atomic hydrogen
B H<sub>2</sub> is an inherently unstable molecule that decomposes readily at room temperature
C Free hydrogen atoms are more thermodynamically stable than H<sub>2</sub> molecules
D The dissociation reaction proceeds spontaneously without any energy input
Show answer & explanation
Answer: A. H<sub>2</sub> is thermally stable; significant energy must be supplied to create atomic hydrogen
Why: The high H-H bond dissociation enthalpy means H<sub>2</sub> is very stable thermally; atomic H is highly reactive and rare under normal conditions.
Q73.
Why is water considered a universal solvent?
A High polarity, small size, and ability to hydrogen bond with solutes enables it to dissolve many ionic and polar covalent substances
B Its complete lack of visible colour is what supposedly allows it to dissolve coloured substances so easily as widely reported in standard practice
C Its non-toxic nature toward living cells is supposedly what allows it to dissolve so many different compounds under most conditions encountered
D It happens to have the lowest boiling point of any common liquid solvent used in laboratory chemistry as frequently observed in practice
Show answer & explanation
Answer: A. High polarity, small size, and ability to hydrogen bond with solutes enables it to dissolve many ionic and polar covalent substances
Why: Water's strong polarity and hydrogen-bonding ability stabilise ions (via hydration) and polar solutes, dissolving more substances than any other solvent.
Q74.
Proton transfer reactions (Bronsted acid-base) are fast because:
A Protons (H+) are very small and have no electrons, so tunnelling and fast diffusion in water occur via the Grotthuss mechanism
B Proton transfer reactions proceed with highly zero activation energy barrier at any temperature in many documented cases
C Changing the reaction temperature has little measurable effect on the proton transfer rate according to conventional understanding
D Such reactions occur quickly mainly because bulk liquid water happens to be present nearby in routine practice overall in most cases
Show answer & explanation
Answer: A. Protons (H+) are very small and have no electrons, so tunnelling and fast diffusion in water occur via the Grotthuss mechanism
Why: In water, proton transfer occurs via the Grotthuss mechanism: cooperative H-bond network rearrangements relay protons faster than normal diffusion.
Q75.
The H–H bond enthalpy (436 kJ/mol) is one of the highest for a single bond, which explains why dihydrogen is:
A highly reactive at room temperature
B relatively inert at room temperature
C a powerful oxidising agent overall
D predominantly ionic in character
Show answer & explanation
Answer: B. relatively inert at room temperature
Why: The very strong H–H bond makes dihydrogen kinetically unreactive at room temperature; reactions need heat, light or a catalyst to break the bond.