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🧪 Chemistry  ·  Chemical Kinetics  ·  NEET & JEE

In collision theory, the fraction of molecules possessing energy equal to or greater than the activation energy is represented by the term:

Answer: e -Ea/RT.

  • A e<sup>-Ea/RT</sup>
  • B e<sup>Ea/RT</sup>
  • C Ea/RT
  • D RT/Ea

Correct answer: A. e<sup>-Ea/RT</sup>

Explanation: The Boltzmann factor e<sup>-Ea/RT</sup> gives the fraction of colliding molecules with energy at least equal to the activation energy Ea.

First-Order Decay: Constant Half-Lifetime[A][A]₀[A]₀/22 × t½[A]₀/4Each successive half-life takes the SAME amount of time, regardless of starting concentration

First-order decay curve: concentration halves every t½, and that half-life is constant - a defining test for first-order kinetics.

Concept context

Study the speed of reactions and what affects it: concentration, temperature, and catalysts. Covers rate law, order of reaction, the Arrhenius equation, and reaction mechanisms step by step.

Read the full Chemical Kinetics notes →