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🧪 Chemistry  ·  Amines  ·  NEET & JEE

Which product results from Hofmann elimination of (CH3CH<sub>2</sub>)3N+CH<sub>2</sub>CH<sub>3</sub> OH-?

Answer: Ethene + triethylamine.

  • A Ethene + triethylamine
  • B Ethane + triethylamine
  • C Ethanol + triethylamine
  • D Propene + dimethylamine

Correct answer: A. Ethene + triethylamine

Explanation: Hofmann elimination of tetraethylammonium hydroxide gives ethene (beta elimination) and triethylamine.

Why Aniline Is a Weaker Base Than MethylamineNCH₃lone pair fully availableMethylamineN donates electrons freely → STRONG baseNlone pair delocalised into ringAniline

In aniline, the nitrogen's lone pair is pulled into the benzene ring through resonance, leaving less electron density available to accept a proton - which is why aniline is a much weaker base than methylamine, where the lone pair is fully available.

Concept context

Nitrogen-containing organic compounds. Covers classification (primary, secondary, tertiary), basicity comparison, preparation methods, and reactions including diazotization and coupling, key for understanding dyes and pharmaceuticals.

Read the full Amines notes →