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🧪 Chemistry  ·  Amines  ·  NEET & JEE

Which of the following is a secondary amine?

Answer: Dimethylamine.

  • A Dimethylamine
  • B Methylamine
  • C Trimethylamine
  • D Aniline

Correct answer: A. Dimethylamine

Explanation: Dimethylamine (CH<sub>3</sub>)<sub>2</sub>NH has two methyl groups on nitrogen, making it secondary.

Why Aniline Is a Weaker Base Than MethylamineNCH₃lone pair fully availableMethylamineN donates electrons freely → STRONG baseNlone pair delocalised into ringAniline

In aniline, the nitrogen's lone pair is pulled into the benzene ring through resonance, leaving less electron density available to accept a proton - which is why aniline is a much weaker base than methylamine, where the lone pair is fully available.

Concept context

Nitrogen-containing organic compounds. Covers classification (primary, secondary, tertiary), basicity comparison, preparation methods, and reactions including diazotization and coupling, key for understanding dyes and pharmaceuticals.

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