Zaymiey

🧪 Chemistry  ·  Amines  ·  NEET & JEE

Which compound gives a positive carbylamine test?

Answer: Primary amine.

  • A Primary amine
  • B Secondary amine
  • C Tertiary amine
  • D Quaternary ammonium salt

Correct answer: A. Primary amine

Explanation: Only primary amines give the characteristic foul-smelling isocyanide in the carbylamine test.

Why Aniline Is a Weaker Base Than MethylamineNCH₃lone pair fully availableMethylamineN donates electrons freely → STRONG baseNlone pair delocalised into ringAniline

In aniline, the nitrogen's lone pair is pulled into the benzene ring through resonance, leaving less electron density available to accept a proton - which is why aniline is a much weaker base than methylamine, where the lone pair is fully available.

Concept context

Nitrogen-containing organic compounds. Covers classification (primary, secondary, tertiary), basicity comparison, preparation methods, and reactions including diazotization and coupling, key for understanding dyes and pharmaceuticals.

Read the full Amines notes →