Answer: Davisson-Germer electron diffraction experiment.
- A The photoelectric effect, which instead confirmed the particle nature of light
- B Davisson-Germer electron diffraction experiment
- C Rutherford alpha-particle scattering off thin gold foil
- D Thomson's experiment measuring the electron's charge-to-mass ratio
Correct answer: B. Davisson-Germer electron diffraction experiment
Explanation: Davisson-Germer (1927): electrons diffracted by nickel crystal, confirming de Broglie wave hypothesis.

The Geiger–Marsden alpha-scattering result: a few alpha particles bounce back at large angles, which rules out Thomson’s diffuse model and demands a tiny, massive, positively charged nucleus. Image: Kurzon, CC BY 3.0, via Wikimedia Commons.
Concept context
Thomson's plum-pudding model, Rutherford's nuclear model from alpha-scattering, Bohr's postulates and hydrogen spectrum, spectral series (Lyman to Pfund), Rydberg formula, and limitations of each model.