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⚛️ Physics  ·  Atoms  ·  NEET & JEE

Fine structure of hydrogen spectral lines arises from:

Answer: Spin-orbit coupling (interaction of electron spin with orbital magnetic field).

  • A The recoiling motion of the atomic nucleus during emission as frequently observed in practice
  • B Spin-orbit coupling (interaction of electron spin with orbital magnetic field)
  • C Ordinary Zeeman splitting from an externally applied magnetic field in many documented cases
  • D The gravitational attraction between the electron and the nucleus according to conventional understanding

Correct answer: B. Spin-orbit coupling (interaction of electron spin with orbital magnetic field)

Explanation: Fine structure: spin-orbit interaction. Electron spin magnetic moment interacts with magnetic field seen in electron rest frame. Splits energy levels.

Comparison of the Thomson model and the Rutherford model of the atom: in the Thomson plum pudding model alpha particles pass almost straight through a diffuse positive sphere, while in the Rutherford model a concentrated central nucleus deflects some alpha particles through large angles, with the lower panels showing the alpha particle source and gold foil and the observed result of wide-angle scattering

The Geiger–Marsden alpha-scattering result: a few alpha particles bounce back at large angles, which rules out Thomson’s diffuse model and demands a tiny, massive, positively charged nucleus. Image: Kurzon, CC BY 3.0, via Wikimedia Commons.

Concept context

Thomson's plum-pudding model, Rutherford's nuclear model from alpha-scattering, Bohr's postulates and hydrogen spectrum, spectral series (Lyman to Pfund), Rydberg formula, and limitations of each model.

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