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🧪 Chemistry  ·  Surface Chemistry  ·  NEET & JEE

In delta formation at a river mouth, fine clay and silt particles carried by river water as a negatively charged colloidal sol settle out. What is the most likely chemical reason for this?

Answer: Sea water contains a high concentration of electrolytes whose cations coagulate the negatively charged clay sol.

  • A River water cools suddenly upon meeting the sea, physically freezing the suspended particles according to standard textbooks
  • B Sea water contains a high concentration of electrolytes whose cations coagulate the negatively charged clay sol
  • C Sunlight at the river mouth chemically breaks down the colloidal clay particles in general practice as frequently described
  • D River water evaporates unusually rapidly right at the point it meets the sea in most textbook accounts during normal conditions

Correct answer: B. Sea water contains a high concentration of electrolytes whose cations coagulate the negatively charged clay sol

Explanation: Sea water is rich in dissolved electrolytes (Na+, Mg<sup>2+</sup>, Ca<sup>2+</sup> ions). These cations neutralize the charge on negatively charged clay colloids from river water, causing coagulation and the buildup of a delta.

Adsorption Isotherm: x/m vs PressureP (pressure)x/mlow P: x/m ∝ Phigh P: saturation plateauAt high pressure, all surface sites are occupied - the curve flattens (monolayer saturation)

A typical adsorption isotherm: x/m (mass adsorbed per gram of adsorbent) rises steeply at low pressure, then flattens into a saturation plateau as the adsorbent surface fills up.

Concept context

Explore the chemistry that happens at interfaces, from catalysts that speed up industrial reactions to colloids like milk, smoke, and gels that surround us every day.

Read the full Surface Chemistry notes →