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🧪 Chemistry  ·  Surface Chemistry  ·  NEET & JEE

Gold sol prepared by reduction of gold salts is stabilized by adsorbed negative ions on its surface. If a small amount of a strongly hydrated lyophilic colloid such as gelatin is added before adding an electrolyte, the gold sol becomes more resistant to coagulation. This protective effect is best explained by:

Answer: Gelatin forms a protective hydrophilic coating around the lyophobic gold particles, reducing their tendency to aggregate.

  • A Gelatin is said to completely and permanently neutralize the entire surface charge carried by every gold particle present
  • B Gelatin forms a protective hydrophilic coating around the lyophobic gold particles, reducing their tendency to aggregate
  • C Gelatin is said to chemically react directly with the gold atoms themselves to form a brand new compound
  • D Gelatin is said to noticeably raise the temperature of the surrounding sol, and this is what prevents coagulation

Correct answer: B. Gelatin forms a protective hydrophilic coating around the lyophobic gold particles, reducing their tendency to aggregate

Explanation: This is known as protective colloid action: a lyophilic colloid like gelatin coats lyophobic particles such as gold, providing a hydrated protective layer that resists coagulation, the basis of the gold number concept.

Adsorption Isotherm: x/m vs PressureP (pressure)x/mlow P: x/m ∝ Phigh P: saturation plateauAt high pressure, all surface sites are occupied - the curve flattens (monolayer saturation)

A typical adsorption isotherm: x/m (mass adsorbed per gram of adsorbent) rises steeply at low pressure, then flattens into a saturation plateau as the adsorbent surface fills up.

Concept context

Explore the chemistry that happens at interfaces, from catalysts that speed up industrial reactions to colloids like milk, smoke, and gels that surround us every day.

Read the full Surface Chemistry notes →