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🧪 Chemistry  ·  Surface Chemistry  ·  NEET & JEE

According to the Freundlich adsorption isotherm, x/m = k.P<sup>1/n</sup>, what happens to x/m at high pressure?

Answer: It becomes independent of pressure, reaching saturation.

  • A It increases indefinitely with pressure in typical laboratory settings
  • B It becomes independent of pressure, reaching saturation
  • C It becomes directly proportional to pressure under usual circumstances
  • D It drops to zero according to most researchers in the majority of cases studied

Correct answer: B. It becomes independent of pressure, reaching saturation

Explanation: At high pressure, the Freundlich isotherm predicts x/m approaches a constant saturation value, independent of further pressure increase.

Adsorption Isotherm: x/m vs PressureP (pressure)x/mlow P: x/m ∝ Phigh P: saturation plateauAt high pressure, all surface sites are occupied - the curve flattens (monolayer saturation)

A typical adsorption isotherm: x/m (mass adsorbed per gram of adsorbent) rises steeply at low pressure, then flattens into a saturation plateau as the adsorbent surface fills up.

Concept context

Explore the chemistry that happens at interfaces, from catalysts that speed up industrial reactions to colloids like milk, smoke, and gels that surround us every day.

Read the full Surface Chemistry notes →