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🧪 Chemistry  ·  Surface Chemistry  ·  NEET & JEE

A colloidal sol of As<sub>2</sub>S<sub>3</sub> is negatively charged. Which combination correctly ranks the coagulating power of NaCl, MgCl<sub>2</sub>, and AlCl<sub>3</sub> from least to most effective, based on the Hardy-Schulze rule?

Answer: NaCl less than MgCl 2 less than AlCl 3.

  • A AlCl<sub>3</sub> less than MgCl<sub>2</sub> less than NaCl
  • B NaCl less than MgCl<sub>2</sub> less than AlCl<sub>3</sub>
  • C MgCl<sub>2</sub> less than NaCl less than AlCl<sub>3</sub>
  • D All three are equally effective regardless of cation charge

Correct answer: B. NaCl less than MgCl<sub>2</sub> less than AlCl<sub>3</sub>

Explanation: Coagulating power increases with the valency of the oppositely charged ion. Since the sol is negative, cations matter: Na+ (1+) is weakest, Mg<sup>2+</sup> (2+) is intermediate, and Al<sup>3+</sup> (3+) is the strongest coagulant.

Adsorption Isotherm: x/m vs PressureP (pressure)x/mlow P: x/m ∝ Phigh P: saturation plateauAt high pressure, all surface sites are occupied - the curve flattens (monolayer saturation)

A typical adsorption isotherm: x/m (mass adsorbed per gram of adsorbent) rises steeply at low pressure, then flattens into a saturation plateau as the adsorbent surface fills up.

Concept context

Explore the chemistry that happens at interfaces, from catalysts that speed up industrial reactions to colloids like milk, smoke, and gels that surround us every day.

Read the full Surface Chemistry notes →