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🧪 Chemistry  ·  Solid State  ·  NEET & JEE

Which of the following oxides behaves as an n-type semiconductor?

Answer: ZnO.

  • A NiO
  • B Cu<sub>2</sub>O
  • C Fe2O<sub>3</sub>
  • D ZnO

Correct answer: D. ZnO

Explanation: ZnO develops a metal-excess defect on heating: extra Zn²⁺ in interstitial sites with electrons as carriers, making it n-type. NiO and Cu₂O are p-type; Fe₂O₃ behaves differently.

Cubic Unit Cells: Atom PositionsSimple CubicCN=6, 52.4% packedBody-Centred (BCC)CN=8, 68% packedFace-Centred (FCC)CN=12, 74% packed (densest)Corner atoms (shared by 8 cells) shown lighter; body/face-centre atoms shown solid

The three cubic unit cells: Simple Cubic has atoms only at corners; Body-Centred adds one atom at the centre; Face-Centred adds one atom at the centre of each of the 6 faces, giving the highest packing efficiency.

Concept context

Explore the ordered world of crystalline solids: unit cells, packing, defects, and how structure determines electrical and magnetic properties.

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