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🧪 Chemistry  ·  Solid State  ·  NEET & JEE

When NaCl is doped with 10-3 mol% of SrCl2, the number of cation vacancies per mole of NaCl is (NA = 6.022 x 1023):

Answer: 6.022 x 1018.

  • A 6.022 x 1016
  • B 6.022 x 1020
  • C 6.022 x 1018
  • D 1.2 x 1019

Correct answer: C. 6.022 x 1018

Explanation: Each Sr2+ replaces two Na+ but occupies one site, creating one vacancy. 10-3 mol% = 10-5 mol, so vacancies = 10-5 x NA = 6.022 x 1018.

Cubic Unit Cells: Atom PositionsSimple CubicCN=6, 52.4% packedBody-Centred (BCC)CN=8, 68% packedFace-Centred (FCC)CN=12, 74% packed (densest)Corner atoms (shared by 8 cells) shown lighter; body/face-centre atoms shown solid

The three cubic unit cells: Simple Cubic has atoms only at corners; Body-Centred adds one atom at the centre; Face-Centred adds one atom at the centre of each of the 6 faces, giving the highest packing efficiency.

Concept context

Explore the ordered world of crystalline solids: unit cells, packing, defects, and how structure determines electrical and magnetic properties.

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